Published October 4, 2021 | Version v1
Conference proceeding Open

Ruthenium-Exsolution Catalyst for Dry Reforming of Biogas

Description

When biogases are directly used as fuels in SOFCs, catalytic reforming of methane into hydrogen and carbon monoxide occurs at the nickel anode. This may expose the anode to localized cooling and high risk of carbon deposition. These issues can be tackled by preprocessing the biogas. Diluting it with steam or CO2 recovered from the SOFC anode off-gas may suppress the risk of carbon deposition whereas reforming it externally can protect the cell from thermal instabilities while offering additional protection against contaminants. Ruthenium has an outstanding catalytic activity with demonstrated coking resistance. Its cost however limits its use. In this work, dry reforming of diluted biogases was performed on a low-ruthenium-exsolution catalyst. An approach by total material balance allowed to determine near 100 % methane conversion at GHSV up to 2000 h-1 while the reaction was close to the computed thermodynamic equilibrium.

Files

No6_Ruthenium-Exsolution Catalyst for Dry Reforming of Biogas.pdf

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Additional details

Funding

European Commission
WASTE2WATTS - Unlocking unused bio-WASTE resources with loW cost cleAning and Thermal inTegration with Solid oxide fuel cells 826234

Dates

Accepted
2021-10-04

References

  • Frantz, C., Rumpf, L., Solá, A. L., Wang, L., Naeem, M. A., Müller, C. R., & Van Herle, J. (2021). Ruthenium-Exsolution Catalyst for Dry Reforming of Biogas. ECS Transactions, 103(1), 1563.