Stable Sn-Based Hybrid Perovskite-Related Structures with Tunable Color Coordinates via Organic Cations in Low-Temperature Synthesis
Creators
- 1. QustomDot
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2.
University of Pisa
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3.
Italian Institute of Technology
- 4. Istituto Italiano di Tecnologia Ceneter for Materials Interfaces
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5.
University of Milano-Bicocca
- 6. US Environmental Protection Agency Office of Research and Development
Description
Organic–inorganic Pb-free layered perovskites are efficient broadband emitters and thus are promising materials for lighting applications. However, their synthetic protocols require a controlled atmosphere, high temperature, and long preparation time. This hinders the potential tunability of their emission through organic cations, as is instead common practice in Pb-based structures. Here, we present a set of Sn–Br layered perovskite-related structures that display different chromaticity coordinates and photoluminescence quantum yield (PLQY) up to 80%, depending on the choice of the organic monocation. We first develop a synthetic protocol that is performed under air and at 4 °C, requiring only a few steps. X-ray and 3D electron diffraction analyses show that the structures exhibit diverse octahedra connectivity (disconnected and face-sharing) and thus optical properties, while preserving the organic–inorganic layer intercalation. These results provide key insight into a previously underexplored strategy to tune the color coordinates of Pb-free layered perovskites through organic cations with complex molecular configurations.
Files
prabhakaran-et-al-2023-stable-sn-based-hybrid-perovskite-related-structures-with-tunable-color-coordinates-via-organic.pdf
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Additional details
Funding
Dates
- Submitted
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2025-06-12
Software
- Repository URL
- https://doi.org/10.1021/acsenergylett.3c00791