Published June 30, 1963
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Decomposition of Ce(IV) Chloride Complex : Kinetic Study in Perchloric Acid Medium
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The rod-coloured complex formed by the interaction of ceric perchlorate and HCl in a high concentration of HC1 is unstable and decomposes gradually. The kinetics of the decomposition obeys first order law. The activation energy and the entropy of activation are found to be 6.3 kcals./mole and — 38 (E.U.) respectively.
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