Published October 5, 2020 | Version v1
Conference paper Open

A Study on the Integration of a Sodium Borohydride (NaBH4) Fuelled Hybrid System for a Small Inland Vessel

Creators

  • 1. Delft University of Technology, The Netherlands;

Description

The use of fuel cells as a power source for propulsion can reduce the thermal and noise signatures of naval vessels drastically. However, safe and high energy-dense storage of hydrogen prevents this technology from being widely used. In this paper, a battery and hydrogen hybrid propulsion system fueled by NaBH4 for a small inland vessel is designed and evaluated using MATLAB Simulink modelling. NaBH4 is a hydrogen carrier that can react with water to produce pure hydrogen. The water can be produced on-board resulting in a high-density hydrogen storage option. In addition, the solid form of NaBH4 is stable under atmospheric conditions, leading to a safe hydrogen storage option. The effectiveness of the system is studied by defining three operational profiles and using these profiles as inputs to size the energy storage components. To regulate the power between storage components, an energy management strategy (EMS) is implemented. Finally, different configurations are used to estimate the energy density of the system. The highest energy density is found at 1.2 kWh/ kg and 1.3 kWh/L of hydrogen for a 100-hour range using solid NaBH4. The results implicate that using onboard produced water for the hydrolysis of NaBH4 can enable a safe, and energy-dense hydrogen storage unique to the maritime industry.

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References

  • PP Edwards, VL Kuznetsov, and WIF David. Hydrogen energy. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 365(1853):1043–1056, 2007.
  • Jeff Baldic, Paul Osenar, Nick Lauder, and Peter Launie. Fuel Cell systems for long duration electric UAVs and UGVs. Defense Transformation and Net-Centric Systems 2010, 7707(May):031–039, 2010.
  • Kyunghwan Kim, Taegyu Kim, Kiseong Lee, and Sejin Kwon. Fuel cell system with sodium borohydride as hydrogen source for unmanned aerial vehicles. Journal of Power Sources, 196(21):9069–9075, 2011.
  • Taegyu Kim. NaBH4 (sodium borohydride) hydrogen generator with a volume-exchange fuel tank for small unmanned aerial vehicles powered by a PEM (proton exchange membrane) fuel cell. Energy, 69:721–727, 2014.
  • Soon-mo Kwon, Shinuang Kang, and Taegyu Kim. Development of NaBH4-Based Hydrogen Generator for Fuel Cell Unmanned Aerial Vehicles with Movable Fuel Cartridge. Energy Procedia, 158:1930–1935, 2019.
  • Valentina G. Minkina, Stanislav I. Shabunya, Vladimir I. Kalinin, and Alevtina Smirnova. Hydrogen generation from sodium borohydride solutions for stationary applications. International Journal of Hydrogen Energy, 41(22):9227–9233, jun 2016.
  • U.S. Department of Energy. Technical Targets for Onboard Hydrogen Storage for Light-Duty Vehicles. https://www.energy.gov/eere/fuelcells/fuel-cell-technologies-office, 2019. Accessed: 19-05-2020.
  • J´erˆome Andrieux, Laetitia Laversenne, Olesia Krol, Rodica Chiriac, Zeinab Bouajila, Richard Tenu, Jean Jacques Counioux, and Christelle Goutaudier. Revision of the NaBO2–H2O phase diagram for optimized yield in the H2 generation through NaBH4 hydrolysis. international journal of hydrogen energy, 37(7):5798–5810, 2012.
  • Aslı Boran, Serdar Erkan, and Inci Eroglu. Hydrogen generation from solid state nabh4 by using fecl3 catalyst for portable proton exchange membrane fuel cell applications. International Journal of Hydrogen Energy, 44(34):18915–18926, 2019.
  • Umit Bilge Demirci, O Akdim, J´erˆome Andrieux, Julien Hannauer, Rita Chamoun, and Philippe Miele. Sodium borohydride hydrolysis as hydrogen generator: issues, state of the art and applicability upstream from a fuel cell. Fuel Cells, 10(3):335–350, 2010.
  • Reza Dashtpour and Sarim N Al-zubaidy. Energy Efficient Reverse Osmosis Desalination Process. International Journal of Enviromental Science and Development, 3(4):339–345, 2012.
  • Olivier Tremblay, Louis-A Dessaint, et al. A generic fuel cell model for the simulation of fuel cell vehicles. In 2009 IEEE Vehicle Power and Propulsion Conference, pages 1722–1729. IEEE, 2009.
  • Olivier Tremblay and Louis-A Dessaint. Experimental validation of a battery dynamic model for EV applications. World electric vehicle journal, 3(2):289–298, 2009.