Published February 25, 2024
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Hypervalent Iodine: Introduction, Synthesis and its Applications
Authors/Creators
- 1. Department of Chemistry, Abasaheb Marathe Arts & New Commerce, Science College, Rajapur, Ratnagiri 416702, Maharashtra, India
Description
Hyper iodine reagents are readily available, easy preparative procedures, and
mild reactivity with good stability. The hypervalent iodine reagents have become regents
of interest to organic chemists. They can be used for many transformations like ring
expansion reaction, ring closure reaction, single electron transfer reaction, oxidation etc.
in this chapter study literature on hypervalent iodine compounds, their synthesis and
applications are listed.
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2024-02-25Book Chapter
References
- Musher, J. I. The Chemistry of Hypervalent Molecules. Angewandte Chemie International Edition 1969, 8, 54–68. 2. Varvoglis, A, A. The Organic Chemistry of Polycoordinated Iodine; VCH Publishers, Inc.: New York, 1992 3. Harding, M.M.; Abeysinghe, P.M.; Han, Y. Oxidation of threonine residues with IBX reagents. Tetrahedron Letters 2009, 50, 2601 – 2604. 4. Hara, S.; Sawaguchi, M.; Ayuba, S. A Practical Synthetic Method of Iodoarene Difluorides without Fluorine Gas and Mercury Salts. Synthesis 2002,13,1802-1803 ISBN 978-81-959483-9-0, Emerging Trend in Sciences and Allied Sciences (ETISAS-2024) Pub. Date: 25/02/2024 Web: https://naturelightpublications.com 299 Hypervalent Iodine: Introduction, Synthesis and its Applications 5. Wirth, T. Angewandte Chemie International Edition 2005, 44, 3656. 6. DiMagno, S. G.; Sun, H.; Wang, B. Method for Detecting Water in Organic Solvents. Organic Letters 2008, 10, 4413–4416. 7. Katzenellenbogen, J. A.; Lee, B. C.; Lee, K. C.; Lee, H.; Mach, R. H. Strategies for the Labeling of Halogen-Substituted Peroxisome Proliferator-Activated Receptor γ Ligands: Potential Positron Emission Tomography and Single Photon Emission Computed Tomography Imaging Agents. Bioconjugate Chemistry 2007, 18, 514– 523 8. Togo, H.; Abe, S.; Sakuratani, K. Synthetic Use of Poly[4-hydroxy(tosyloxy)iodo] styrenes. Journal of Organic Chemistry 2001, 66, 6174-6177. 9. Togo, H.; Nabana, T. Reactivities of Novel [Hydroxy (tosyloxy) iodo] arenes and [Hydroxy (phosphoryloxy) iodo] arenes for α-Tosyloxylation and αPhosphoryloxylation of Ketones. Journal of Organic Chemistry 2002, 67, 4362– 4365. 10. Togo, H.; Sakuratani, K. Polymer-Supported Hypervalent Iodine Reagents. Synlett 2002,12,1966-1975 11. Togo, H.; Yamamoto, Y. Facile One-Pot Preparation of [Hydroxy (sulfonyloxy) iodo] arenes from -Iodoarenes with MCPBA in the Presence of Sulfonic Acids. Synlett 2005, 16, 2486-2488. 12. Yusubov, M.S.; Yusubova, R.Y.; Funk, T.Y.; Chi, K.W.; Zhdankin, V.V. Oligomeric Iodoxybenzene Sulfate: A Convenient Hypervalent Iodine Reagent for Oxidation of Organic Sulfides and Alkenes. Synthesis 2009, 15, 2505–2508. 13. Huang, X.; Yu, L.; Chen, B. Multicomponent reactions of allenes, diary diselenides, and nucleophiles in the presence of iodosobenzene diacetate: direct synthesis of 3- functionalized-2-arylselenyl substituted allyl derivatives. Tetrahedron Letters 2007, 48, 925-927. 14. Iglesias-Arteaga, M. A.; Arcos-Ramos, R. O. One-step axial acetoxylation at C-23. A new method for the functionalization of the side chain of steroid sapogenins. Tetrahedron Letters 2006, 47, 8029-8031. 15. Iglesias-Arteaga, M. A.; Arcos-Ramos, R. O.; Mendez-Stivalet, J. M. The unexpected course of the reaction of steroid sapogenins with diacetoxyiodobenzene and BF3·Et2O in formic acid. Tetrahedron Letters 2007, 48, 7485-7488. 16. Tellitu, I.; Correa, A.; Dominguez, E.; SanMartin, R. A Metal-Free Approach to the Synthesis of Indoline Derivatives by Phenyliodine (III) Bis (trifluoroacetate)- Mediated Amidohydroxylation Reaction. Journal of Organic Chemistry 2006,71,8316–8319