Published September 9, 2020
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A Toroidal Zr70 Oxysulfate Cluster and Its Diverse Packing Structures
Authors/Creators
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1.
University of Oslo
Description
A toroidal Zr(IV) oxysulfate cluster of unprecedented size with the formula Zr70(SO4)58(O/OH)146⋅x (H2O) (Zr70) was synthesized. Depending on the co-crystallizing species, it displays different packing of the ring units. One of the phases contains one-dimensional channels through the rings, showing high permanent porosity (surface area: 241 m2 g−1). The ring entity measures over 3 nm across and displays a pseudo-10-fold rotational symmetry.
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Angew Chem Int Ed - 2020 anie202010847.pdf
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- Dataset: 10.5281/zenodo.10038278 (DOI)