Copper Carbazole Diphosphonate - 2
Creators
- 1. CAU
- 2. JGU
- 3. SU
- 4. UP
Description
CAU-37-act
The following submission contains the data collection and processing for the sample CAU-37-act in the framework of the publication: Synthesis and Structure Evolution in Metal Carbazole Diphosphonates Followed by Electron Diffraction. Felix Steinke, Laura Gemmrich Hernandéz, Stephen J. I. Shearan, Maxi Pohlmann, Marco Taddei, Ute Kolb, and Norbert Stock. Inorganic Chemistry 2023 62 (1), 35-42.
Precession Electron Diffraction (PED) was used to collect the dataset on the target crystal. The dataset was processed with PETS2 and eADT software. The table below summarizes the data collection parameters for the dataset.
|
General information: |
|
|
|
Project |
|
NanED (www.naned.eu) |
|
ESR Project |
|
ESR8 |
|
Project Label |
|
CAU-37 |
|
Sample Label |
|
CAU-37-act |
|
Data set Label |
|
CuDPC_Cry6 |
|
|
|
|
|
Instrumental: |
|
|
|
Instrument |
|
FEI TECNAI F30 STWIN |
|
Radiation source |
|
FEG |
|
Accelerating voltage |
|
300 kV |
|
Wavelength |
|
0.0197 Å |
|
Probe Type |
|
Nanodiffraction |
|
Beam Diameter |
|
200nm |
|
Beam Convergence |
|
Semi-parallel beam |
|
Detector |
|
US4000 - CCD camera GATAN (16-bit) (bottom mounted) |
|
Number of pixels in the image |
|
2048 x 2048 |
|
Pixel size |
|
15 µm x 15 µm |
|
Camera Length / Effective Camera Length |
|
1500 mm / 1500 mm |
|
Calibration constant (not corrected for Effective Camera length) |
|
0.00074 Å-1/pixel |
|
Hardware Binning |
|
2 |
|
Sample description: |
|
|
|
Name |
|
CAU-37-act |
|
Chemical composition |
|
[Cu2(H2O)2(L)]∙2H2O] 3,6-diphosphono-9H-carbazole (H4L) |
|
Sample source |
|
Synthesized |
|
Sample preparation |
|
Grinded in an Agatha mortar and suspended in 1ml of EtOH. 4 µL of the suspension were dropped with a pipette on the carbon side of a carbon-coated copper grid (300 mesh). |
|
Experimental: |
|
|
|
Data Type |
|
Electron diffraction data - 3D ED |
|
Data collection method |
|
Precession |
|
Temperature (K) used during data collection |
|
293 K |
|
Number of crystals contributing to the data set |
|
1 |
|
Number of experimental frames |
|
121 |
|
tilt range, tilt step, tilt per frame |
|
-60° to +60°, 1°, 0° |
|
Precession angle |
|
1° |
|
Exposure time per frame |
|
4 s |
|
|
|
|
|
Software: |
|
|
|
Software used for the data collection |
|
Gatan Digital Micrograph software |
|
Software used for processing |
|
PETS2 and eADT |
|
|
|
|
|
Authorship and bibliography |
|
|
|
Author(s) of the data |
|
Laura Gemmrich Hernández (ESR8) |
|
Related data |
|
CAU-37-as & CAU-57 |
|
Publication(s) |
|
https://doi.org/10.1021/acs.inorgchem.2c02599 |
|
|
|
|
|
Files and data formats |
|
|
|
Image folder |
|
img: Folder containing images of the diffraction pattern from each frame. |
|
Image format |
|
tiff_16bit_unsigned |
|
|
Files
Files
(474.6 MB)
| Name | Size | Download all |
|---|---|---|
|
md5:841b88b6ba2ded8d4c4950de865b2756
|
474.6 MB | Download |