Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy

Published March 2, 2023 | Version v1

Dataset Open

1. Felix Bloch Institute for Solid State Physics, Universität Leipzig, Linnéstr. 5, 04103 Leipzig, Germany
2. Department of Inorganic Chemistry, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany
3. School of Chemistry, Cardiff University, Park Place, Cardiff CF10 3AT, United

Data type: Experimental spectroscopic measurements, computer simulation and analysis
Files are with filename extensions: DSC, DAT, m, txt
Information on origin of the data:

X-band CW-EPR spectroscopic measurements were generated by EMX spectrometer equipped with SHQ cavity produced by Bruker.
If the dataset includes multiple files that relate to each other:
- Files in PARACAT_WP4_20201111_ULEI_21_DUT49Mn@7K folder includes X-band CW-EPR spectroscopic measurements; original data are in DTA/DSC and txt formats.
- Files in PARACAT_WP4_20201111_ULEI_00_DUT49Mn@simulation folder includes computer simulations/analyses of the EPR measurements; data are in m and txt formats.
Information on:
- specialized abbreviations: DUT49Cu – DUT-49(Cu) MOF, DUT49Mn – DUT-49(Mn) MOF, DUT49CuZn – DUT-49(CuZn) MOF, DUT49MnCu – DUT-49(MnCu) MOF.
- @10K – measured at 10 K
- definitions of variables: Magnetic field, Temperature.

units of measurement: Gauss (G), K, degree (°), milliTesla (mT).

Notes

 Files with extension .m are Matlab input files. Matlab license can be acquired at the link https://it.mathworks.com/downloads/web_downloads/

Name	Size	Download all
Magnetic coupling of divalent metal centers in postsynthetic metal exchanged bimetallic DUT-49 MOFs by EPR spectroscopy.zip md5:270bd9f765a8715f49609c1bcc194920	10.8 MB	Preview Download

European Commission
PARACAT - Paramagnetic Species in Catalysis Research. A Unified Approach Towards Heterogeneous, Homogeneous and Enzyme Catalysis 813209