Influence of Framework n(Si)/n(Al) Ratio on the Nature of Cu Species in Cu-ZSM-5 for NH3-SCR-DeNOx

Published February 28, 2023 | Version V1

Dataset Open

1. Institute of Chemical Technology, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany
2. Faculty of Chemistry, Jagiellonian University in Krakow, Gronostajowa 2, 30-387 Krakow, Poland
3. Felix Bloch Institute for Solid State Physics, Universität Leipzig, Linnéstr. 5, 04103 Leipzig, Germany
4. Laboratory for the Synthesis of New Materials, Division of Materials Chemistry, Ruđer Bošković Institute, Bijenička 54, 10000 Zagreb, Croatia

Data type: Experimental spectroscopic measurements, computer simulation and analysis
Files are with filename extensions: DSC, DAT, m, txt
Information on origin of the data:

X-band CW-EPR spectroscopic measurements were generated by EMX spectrometer equipped with SHQ cavity produced by Bruker.
If the dataset includes multiple files that relate to each other:
- Files in PARACAT_WP3_20220705_01_CW_Experimental folder includes X-band CW-EPR spectroscopic measurements; original data are in DTA/DSC and txt formats.
- Files in PARACAT_WP3_20220705_02_CW_Simulations folder includes computer simulations/analyses of the EPR measurements; data are in m and txt formats.
Information on:
- specialized abbreviations: EPR – Electron Paramagnetic Resonance, CW – Continuous Wave EPR, exp – experimental data, hyd – cw-EPR spectra related to hydrated state, dehyd – cw-EPR spectra related to the dehydrated state, sim – simulation data. Sys – copper species used for constructing the spin-Hamiltonian in EPR simulations. Cu-ZSM-5-com – commercial Cu-ZSM-5. Cu-ZSM-5-100 – Cu-ZSM-5 synthesized at 100 °C. Cu-ZSM-5-120 – Cu-ZSM-5 synthesized at 120 °C. Cu-ZSM-5-150 – Cu-ZSM-5 synthesized at 150 °C.
– Cu-ZSM-5 synthesized at 170 °C.
- definitions of variables: Magnetic field, Temperature.
- units of measurement: Gauss (G), K, degree (°), milliTesla (mT).

Notes

 Files with extension .m are Matlab input files. Matlab license can be acquired at the link https://it.mathworks.com/downloads/web_downloads/

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Influence of Framework n(Si)n(Al) Ratio on the Nature of Cu S_pecies in Cu-ZSM-5 for NH3-SCR-DeNOx.zip md5:2df864828964a45f20488b6d2ac69a02	1.1 MB	Preview Download

European Commission
PARACAT - Paramagnetic Species in Catalysis Research. A Unified Approach Towards Heterogeneous, Homogeneous and Enzyme Catalysis 813209