Published March 31, 2022
| Version v1
Journal article
Open
A ferric guest inside a spin crossover ferrous helicate
Creators
- 1. Universitat de Barcelona
- 2. Universidad de Zaragoza
Description
A designed dimetallic Fe(II) helicate made with biphenylene-bridged
bispyrazolylpyridine ligands and exhibiting a process of spin crossover
at temperatures above ambient is shown to encapsulate an S = 5/2
tris-oxalato Fe(III) ion. The spin relaxation dynamics of this guest are
strongly reduced upon encapsulation.
Files
FATMOLS-UB-Aromi-CHEMCOMM-2022A-Fig2_left.txt
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