Published June 30, 2022 | Version v1
Journal article Open

Development of methods of operative determination of parameters of repeated hydrate formation in layer systems of gas hydrate deposits

  • 1. National University «Yuri Kondratyuk Poltava Polytechnic»

Description

The object of research is the methods of laboratory setting of the parameters of hydrate formation of well production and the design features of the equipment for its implementation. Methane hydrate is becoming a promising topic for a new energy resource. At the same time, hydrostatic formation is one of the most problematic areas in ensuring the transport of well products, and this primarily concerns the production of gas hydrate deposits. An analysis of the thermobaric parameters of the well production of gas hydrate deposits shows that when they are moved by technological lines, they are close to hydrate equilibrium, but due to the intensity of the process, the system does not have time to reach it. In addition, reservoir system water has a memory of hydrate structures, or a certain amount of gas hydrate solid phase is also present in the flow water. In this regard, a set of laboratory studies was carried out to assess the nature of the behavior of this type of systems during the re-crystallization of gas hydrate and its dissociation. Based on the results of the research, a method for the operational laboratory setting of the parameters of repeated hydrate formation in reservoir systems of gas hydrate deposits was developed. It provides for setting the parameters of mass crystallization of gas hydrate by visual fixation of the moment of appearance of the solid phase at the interfacial contact «liquid – gas». The design features of the laboratory facility for its implementation have also been developed and substantiated. The technique makes it possible to reduce the duration of the study of one sample by almost an order of magnitude (from several days to 8–10 hours). In addition to the information on the equilibrium parameters of hydrostatic formation, provided by traditional methods of laboratory research, an additional characteristic of the behavior of reservoir systems in non-equilibrium conditions has been obtained, which will help to quickly assess the risks of technogenic hydrate formation. The developed technique is important for systems that, at least, have a memory of hydrate structures. However, the preliminary transfer of a part of the water of the test sample through the gas hydrate form allows estimating the parameters of hydrate formation of any reservoir system.

Files

Development of methods of operative determination of parameters of repeated hydrate formation in layer systems of gas hydrate deposits.pdf

Additional details

References

  • Kvenvolden, K. A. (1993). Gas hydrates-geological perspective and global change. Reviews of Geophysics, 31 (2), 173–187. doi: http://doi.org/10.1029/93rg00268
  • Sloan, E. D., Jr., Koh, C., Sum, A. K. (2009). Natural Gas Hydrates in Flow Assurance. Colorado School of Mines, Summer workshop. Available at: http://hydrates.mines.edu/CHR/Workshop_files/Natural%20Gas%20Hydrates%20Workshop%202009.pdf
  • Makogon, Y. F. (2010). Natural gas hydrates – A promising source of energy. Journal of Natural Gas Science and Engineering, 2 (1), 49–59. doi: http://doi.org/10.1016/j.jngse.2009.12.004
  • Boswell, R., Collett, T. S. (2011). Current perspectives on gas hydrate resources. Energy Environ. Sci., 4 (4), 1206–1215. doi: http://doi.org/10.1039/c0ee00203h
  • Chong, Z. R., Yang, S. H. B., Babu, P., Linga, P., Li, X.-S. (2016). Review of natural gas hydrates as an energy resource: Prospects and challenges. Applied Energy, 162, 1633–1652. doi: http://doi.org/10.1016/j.apenergy.2014.12.061
  • Kinnari, K., Hundseid, J., Li, X., Askvik, K. M. (2014). Hydrate Management in Practice. Journal of Chemical & Engineering Data, 60 (2), 437–446. doi: http://doi.org/10.1021/je500783u
  • Van derWaals, J. H., Platteeuw, J. C. (1958). Clathrate solutions. Advances in Chemical Physics, 2, 1–57. doi: http://doi.org/10.1002/9780470143483.ch1
  • Klapproth, A., Goreshnik, E., Staykova, D., Klein, H., Kuhs, W. F. (2003). Structural studies of gas hydrates. Canadian Journal of Physics, 81 (1-2), 503–518. doi: http://doi.org/10.1139/p03-024
  • Najibi, H., Kamali, Z., Mohammadi, A. H. (2013). Phase equilibria of carbon dioxide clathrate hydrates in the presence of methanol/ethylene glycol+single salt aqueous solutions: experimental measurement and prediction. Fluid Phase Equilibria, 342, 71–74. doi: http://doi.org/10.1016/j.fluid.2013.01.001
  • Ohmura, R., Ogawa, M., Yasuoka, K., Mori, Y. H. (2003). Statistical Study of Clathrate-Hydrate Nucleation in a Water/Hydrochlorofluorocarbon System: Search for the Nature of the «Memory Effect». The Journal of Physical Chemistry B, 107 (22), 5289–5293. doi: http://doi.org/10.1021/jp027094e
  • Sefidroodi, H., Abrahamsen, E., Kelland, M. A. (2013). Investigation into the strength and source of the memory effect for cyclopentane hydrate. Chemical Engineering Science, 87, 133–140. doi: http://doi.org/10.1016/j.ces.2012.10.018
  • Oyama, H., Konno, Y., Masuda, Y., Narita, H. (2009). Dependence of Depressurization-Induced Dissociation of Methane Hydrate Bearing Laboratory Cores on Heat Transfer. Energy & Fuels, 23 (10), 4995–5002. doi: http://doi.org/10.1021/ef900179y
  • Sira, J., Patil, S., Kamath, S. (1990). Study of hydrate dissociation by methanol and glycol injection. SPE annual technical conference and exhibition. Society of Petroleum Engineers, 977–984. doi: http://doi.org/10.2118/20770-ms
  • Song, Y., Cheng, C., Zhao, J., Zhu, Z., Liu, W., Yang, M., Xue, K. (2015). Evaluation of gas production from methane hydrates using depressurization, thermal stimulation and combined methods. Applied Energy, 145, 265–277. doi: http://doi.org/10.1016/j.apenergy.2015.02.040
  • Shouwei, Z., Wei, C., (2014). Qingping. The green solid fluidization development principle of natural gas hydrate stored in shallow layers of deep water. China Offshore Oil Gas, 26 (5), 1–7.
  • Wu, Q., Lu, J. S., Li, D. L., et al. (2018). Experimental study of mechanical properties of hydrate-bearing sediments during depressurization mining. Rock and Soil Mechanics, 39 (12), 4508–4516.
  • Tohidi, B., Burgass, R. W., Danesh, A., Østergaard, K. K., Todd, A. C. (2006). Improving the Accuracy of Gas Hydrate Dissociation Point Measurements. Annals of the New York Academy of Sciences, 912 (1), 924–931. doi: http://doi.org/10.1111/j.1749-6632.2000.tb06846.x
  • Kumar, R., Wu, H., Englezos, P. (2006). Incipient hydrate phase equilibrium for gas mixtures containing hydrogen, carbon dioxide and propane. Fluid Phase Equilibria, 244 (2), 167–171. doi: http://doi.org/10.1016/j.fluid.2006.04.008
  • Bavoh, C. B., Partoon, B., Lal, B., Kok Keong, L. (2017). Methane hydrate-liquid-vapour-equilibrium phase condition measurements in the presence of natural amino acids. Journal of Natural Gas Science and Engineering, 37, 425–434. doi: http://doi.org/10.1016/j.jngse.2016.11.061
  • Kondo, W., Ohtsuka, K., Ohmura, R., Takeya, S., Mori, Y. H. (2014). Clathrate-hydrate formation from a hydrocarbon gas mixture: Compositional evolution of formed hydrate during an isobaric semi-batch hydrate-forming operation. Applied Energy, 113, 864–871. doi: http://doi.org/10.1016/j.apenergy.2013.08.033
  • Pedchenko, N., Zezekalo, I., Pedchenko, L., Pedchenko, M. (2021). Research into phase transformations in reservoir systems models in the presence of thermodynamic hydrate formation inhibitors of high concentration. E3S Web of Conferences, 230, 01014. doi: http://doi.org/10.1051/e3sconf/202123001014