Published February 29, 1964
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Exchange of Chlorine between Acetyl Chloride and Benzyldimethylphenylammonium Chloride
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Complete exchange of chlorine has been observed between benzyldimethylphenylammoninm chloride containing radioactive chlorine-36 and acetyl chloride within 5 minutes. The results favour self-ionisation of the acetyl chloride.
The self-ionisation of acetyl chloride has boon recently proposed to explain the reactions occurring in this solvent, Acetyl chloride is supposed to ionise as :
\(CH_3COCl \rightleftharpoons CH_3CO^+ +CL^-\)
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