Some New Trans-Bis(Dimethylglyoximato)cobalt(III) Complexes Containing Coordinated Azide-Synthesis and Spectra

Department of Physical Chemistry, University of Madras, Madras 600 025, (INDIA)

Manuscript received 6 September 1917, revised 18 April 1978, accepted 10 May 1918

Some new azidocobaloximes of the general formula \(trans\)-Co(DH)₂LN₃(DH^--^-ON =C(CH₃)-C(CH₃)=N-OH; L-NH₃, aniline, pyridine or \(N_3^-\)] have been synthesized and their i.r and u.v spectra obtained. The u.v. spectra of the conjugate bases of these complexes have also been obtained. A detailed study of the charge-transfer spectra of the complexes and their conjugate bases has been carried out