Published February 4, 2022 | Version v1
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Adsorption of Pb2+ ions in aqueous media using the new zeolite nanocomposite adsorbent CaOCdO/ZSM5 synthesized with new techniques

  • 1. 1Department of Chemistry, Lorestan University, Khorramabad, Iran
  • 2. Departmen of Inorganic Chemistry, Faculty of Chemistry & Petroleum Sciences. Shahid Beheshti University(SBU), Iran

Description

ZSM-5 is a porous zeolite material that reveals good activity for the adsorption of heavy metals and other contaminants for effluent purification. In this scientific research, we synthesized the novel CaOCdO/ZSM-5 zeolite nanocomposite adsorbent and studied the effects of different parameters on the adsorption of Pb2+ ions from water media for the fi rst time. About 99.2% adsorption removal efficiency was obtained after a contact time of 60 min and an adsorbent amount of 0.1g/L for an initial Pb2+ concentration of 200mg/L at pH 8 and temperature of 60oC. The adsorption kinetic fi t well via the pseudo-second-order model. Furthermore, the adsorption results were reproduced using the Langmuir isotherm with a maximum adsorption capacity of mg/g. The thermodynamic data displayed that the adsorption of Pb2+ ions over the CaO-CdO/ZSM-5 nanocomposite was endothermic and spontaneous.

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