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Published December 6, 2021 | Version v1
Journal article Open

RESIDUAL HOLE CONCENTRATION IN RECOMBINATION CENTRES AFTER BLEACHING

  • 1. Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University in Toruń, ul. Grudziądzka 5, 87-100 Toruń, Poland
  • 2. Faculty of Environmental Science and Engineering, Department of Environmental Analysis and Engineering, Babeş-Bolyai University, Cluj-Napoca, Romania

Description

Trapped charge dating method using electron spin resonance (ESR) of quartz is progressively used for sediment
dating. ESR signals can be used for accurate age estimation only when these signals are zeroed by sunlight exposure
before the layer creation or when one knows their ESR residual level (the part of the signal that is not bleached). It
is well known that the ESR signal related to the Al-hole centres in quartz used for sediment dating has a significant
residual signal. From the point of view of luminescence models, as a hole trap, the Al-hole centre is considered as
a recombination centre in quartz. Recently, it was demonstrated experimentally that the ESR signal of the Al-hole
centre is dependent on the total dose absorbed by the quartz sample in the past. The same effect was confirmed by
simulations of the charge transport processes for a model including two recombination centres. Here, the dependence
of residual hole concentration (RHC) in the recombination centres on the total dose absorbed by a sample
in the past is studied in detail by computer simulations for a wide range of model parameters. The impact that the
various relations of centre parameters have on the dependence of the residual as a function of dose is investigated
and the implications for the dating practice are discussed.

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Funding

INTERTRAP – Integrated absolute dating approach for terrestrial records of past climate using trapped charge methods 678106
European Commission