Published May 9, 2017 | Version v1
Journal article Open

A SYSTEMATIC APPROACH FOR THE SEPERATION OF IRON PARTICLES IN SOLUBLE STATE USING LEAF EXTRACT

  • 1. Assistant Professor, Department of Civil Engineering, Sri Ramakrishna Institute of Technology, Coimbatore, Tamilnadu

Description

The discharge of waste water, which contains many minerals like iron, magnesium, zinc etc., from various foundries, steel, dyeing and chemical industries; and treatment plants have substantial effects on the environment and the agricultural lands. Among these metallic elements, iron nanoparticles (FeNPs) have promising advantage that can combat environmental pollution. The interest in nano scale zero-valent iron in environmental remediation is increasing due to the reactivity of nanoscale iron having a large surface area to volume ratio. Though various chemical methods are available for the synthesis of iron nanoparticles, the separation of iron nanoparticles by green route is encouraged as they find various applications in treating the industrial sites contaminated with chlorinated organic compounds and in preventing the ground contaminations. In this project, extracts from various leaves such as Azadirachta indica (neem), Carica papaya (papaya), Punica granatum (pomegranate), Atrocarpus altilis (jackfruit) and Mussaendaerythrophylla (bougainvillea) were used. Randomly, 0.02M ferric chloride solution was prepared as base solution. The reaction between ferric chloride solution and leaf extract have been monitored under UV - Visible spectrophotometer. The effect of various parameters i.e., Dosage, Contact time and pH on the separation of iron nanoparticles in soluble state was studied, by measuring the Absorbance values. The percentage extraction of iron achieved by each leaf extract was determined and finally a comparison among the various leaf extracts used was made and the one which gives the maximum percentage of iron extraction was found out.

Files

CP037.PDF

Files (592.4 kB)

Name Size Download all
md5:352e9e960c17283648dee666fd4507d5
592.4 kB Preview Download

Additional details

References

  • 1. R. R. Banala , V. B. Nagati , P. R. Karnati( September 2015). Green synthesis and characterization of Carica papaya leaf extract coated silver nanoparticles through X-ray diffraction, electron microscopy and evaluation of bactericidal properties, Saudi Journal of Biological Sciences, Vol. 22, pp.637-644. 2. A. Verma, M. S. Mehata(January 2016). Controllable synthesis of silver nanoparticles using Neem leaves and their antimicrobial activity. Journal of Radiation Research and Applied Sciences,Vol. 9, pp.109-115. 3. S.Ahmed, Saifullah, M. Ahmad, B. L. Swami, S. Ikram(January 2016). Green synthesis of silver nanoparticles using Azadirachta indica aqueous leaf extract. Journal of Radiation Research and Applied Sciences,Vol. 9, pp.1-7. 4. M. S. A.Ruqeishi, T. Mohiuddin, L. K. A. Saadi (April 2016). Green synthesis of iron oxide nanorods from deciduous Omani mango tree leaves for heavy oil viscosity treatment. Arabian Journal of Chemistry. 5. A. K. Mittal, Y. Chisti, U. C. Banerjee(April 2013). Synthesis of metallic nanoparticles using plant extracts. Biotechnology Advances ,Vol.31,pp.346-356. 6. E. J.A. Kalifawi (2015). Green synthesis Of Magnetite Iron Oxide Nanoparticles by Using Al-Abbas's (A.S.) Hund Fruit (Citrus medica) var. Sarcodactylis Swingle Extract and Used in Al-'alqami River Water Treatment. Journal Of Natural Sciences Research, Vol 5. 7. S.Shah, S. Dasgupta, M.Chakraborty, R.Vadakkekara, M. Hajoori (July 2014). Green synthesis of iron nanoparticles using plant extracts. International Journal of Biological and Pharmaceutical Research, Vol. 5,pp.549-552. 8. M. Herlekar,S. Barve, R.Kumar(October 2014). Plant Mediated green Synthesis of Iron Nanoparticles. Journal of Nanoparticles,Vol.2014, Volume 2014, Article ID 140614, 9 pages. 9. Z. Wang(2013). Iron complex nanoparticles synthesized by eucalyptus leaves. ACS Sustainable Chemistry and Engineering, vol. 1, pp. 1551–1554. 10. Y. Cai, Y. Shen, A. Xie, S. Li, and X. Wang(2010). Green synthesis of soya bean sprouts-mediated superparamagnetic Fe3O4 nanoparticles. Journal of Magnetism and Magnetic Materials, vol.322, pp. 2938–2943, 2010. 11. S. Machado, S. L. Pinto, J. P. Grosso, H. P. A. Nouws, J. T.Albergaria, and C. Delerue-Matos(2013). Green production of zerovalent iron nanoparticles using tree leaf extracts. Science of the Total Environment, vol. 445-446, pp. 1–8. 12. R.Herrera-Becerra, C. Zorrilla, and J. A. Ascencio(2007). Production of iron oxide nanoparticles by a biosynthesis method: an environmentally friendly route. The Journal of Physical Chemistry,vol. 111, pp. 16147–16153. 13. P.Malik, R. Shankar,V. Malik, N. Sharma, and T K. Mukherjee(March 2014). Green Chemistry Based Benign Routes for Nanoparticle Synthesis. Journal of Nanoparticles.Vol.(2014),14 pages. 14. D.M. Ali, N. Thajuddin, K. Jeganathan, M. Gunasekaran(2011). Plant extract mediated synthesis of silver and gold nanoparticles and its antibacterial activity against clinically isolated pathogens. Colloids Surf B Biointerfaces, Vol.8, 360–5. 15. B. Ankamwar(2010). Biosynthesis of gold nanoparticles (green-gold) using leaf extract of Terminalia catappa. European Journal of Chemistry, Vol.7,pp.1334–9. 16. S. Iravani(2011). Green synthesis of metal nanoparticles using plants. Green Chemistry, Vol.13,pp.2638–50. 17. X. Li, H. Xu, Z.S. Chen, G. Chen (2011). Biosynthesis of nanoparticles by microorganisms and their applications. Journal of Nanomaterial, [article 270974]. 18. K.S. Lin, N.B. Chang, and T.D. Chuang(2008). Fine structure characterization of zero-valent iron nanoparticles for decontamination of nitrites and nitrates in wastewater and groundwater. Science and Technology of Advanced Materials Vol. 9,025015. 19. M. Gui, V. Smuleac, L.E. Ormsbee, D.L. Sedlak, D. Bhattacharyya(April 2012). Iron oxide nanoparticle synthesis in aqueous and membrane systems for oxidative degradation of trichloroethylene from water. Journal of Nanoparticle Research,Vol.14,pp. 1–16.