Published June 20, 2018 | Version v1
Journal article Open

Supported 4-carboxybenzyl sulfamic acid on magnetic nanoparticles as a recoverable and recyclable catalyst for synthesis of 3,4,5-trisubstituted furan-2(5H)-one derivatives

  • 1. Razi University, Department of Organic Chemistry, Kermanshah, 67149-67346, Iran, Nanoscience & Nanotechnology Research Center (NNRC), Razi University, Kermanshah, 67149-67346, Iran Abstract 4-Carboxybenzyl sulfamic acid functionalized Fe3O4 nanoparticles as a novel catalyst was manufactured. This catalyst was characterized and evaluated in the one-pot synthesis of furan-2(5H)-one derivatives from dimethyl acetylenedicarboxylate, aryl aldehydes, and various anilines in terms of activity and reusability. The catalyst showed high catalytic activity, good recoverability and reusability, thermal stability and provides clean production of fine furan-2(5H)-one derivatives in short reaction times. The heterogeneous catalyst could be used at least five times without significant loss of its activity. Keywords: Magnetic nanocatalyst, Aryl aldehydes, Anilines, Dimethyl acetylenedicarboxylate, 4-Carboxybenzyl sulfamic
  • 2. Department of Chemistry, Faculty of Physice & Chemistry, Alzahra University, Vanak, Tehran, Iran, Nanoscience & Nanotechnology Research Center (NNRC)
  • 3. Razi University, Department of Organic Chemistry, Kermanshah, 67149-67346, Iran

Description

4-Carboxybenzyl sulfamic acid functionalized Fe3O4 nanoparticles as a novel catalyst was manufactured. This catalyst was characterized and evaluated in the one-pot synthesis of furan-2(5H)-one derivatives from dimethyl acetylenedicarboxylate, aryl aldehydes, and various anilines in terms of activity and reusability. The catalyst showed high catalytic activity, good recoverability and reusability, thermal stability and provides clean production of fine furan-2(5H)-one derivatives in short reaction times. The heterogeneous catalyst could be used at least five times without significant loss of its activity.

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Supported 4-carboxybenzyl sulfamic acid on magnetic nanoparticles as a recoverable and recyclable catalyst for synthesis of 3,4,5-trisubstituted furan-2(5H)-one derivatives.pdf