Published December 29, 2009 | Version 15759
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Thermodynamic Equilibrium of Nitrogen Species Discharge: Comparison with Global Model

Description

The equilibrium process of plasma nitrogen species by chemical kinetic reactions along various pressures is successfully investigated. The equilibrium process is required in industrial application to obtain the stable condition when heating up the material for having homogenous reaction. Nitrogen species densities is modeled by a continuity equation and extended Arrhenius form. These equations are used to integrate the change of density over the time. The integration is to acquire density and the reaction rate of each reaction where temperature and time dependence are imposed. A comparison is made with global model within pressure range of 1- 100mTorr and the temperature of electron is set to be higher than other nitrogen species. The results shows that the chemical kinetic model only agrees for high pressure because of no power imposed; while the global model considers the external power along the pressure range then the electron and nitrogen species give highly quantity densities by factor of 3 to 5.

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References

  • S. E. Babayan, G. Ding and R. F. Hicks, "Determination of the nitrogen atom density in the afterglow of a nitrogen and helium, nonequilibrium, atmospheric pressure plasma," Plasma Chemistry and Plasma Processing, 21(4)(2001) 505-521
  • J. Park, I. Henins, H. W. Herrmann, and G. S. Selwyn, "An atmospheric pressure plasma source," Appl. Phys. Lett., 76(3)(2000) 288-290
  • L. Yu, Laurent Pierrot, Christophe O. Laux, Charles H. Kruger, "Effects of vibrational nonequilibrium on the chemistry of two-temperature nitrogen plasmas, Plasma Chemistry and Plasma Processing, 21(4)(2001) 483-503
  • Toshiki Nakano, "Some recent topics of non-equilibrium discharge plasma technologies, IEEE Trans. on Dielectrics and Electrical Insulation, 14(5)(2007)1081-1087
  • K.H Becker, U. Kogelschatz, K.H Schoenbach, R.J Barker, "Nonequilibrium air plasmas at atmospheric pressure, IoP Publishing, 2004, page 125-126.
  • E. G. Thorsteinsson and J. T. Gudmundsson, A global (volume averaged) model of the nitrogen discharge: I. Steady State, Plasma Sources Science and Technology, 18 (4) (2009) 045001
  • J Hugill, T Saktioto, A simplified chemical kinetic model for slightly ionized, atmospheric pressure nitrogen plasmas, Plasma Sources Science and Technology, 10 (38) (2001) 38-42
  • Saktioto, A thermodynamic equilibrium of nitrogen plasma species at atmospheric pressure: An application for afterglow, Kontribusi Fisika Indonesia, 13(2)(2002) 104-107
  • IUPAC Compendium of Chemical Terminology, 2nd Edition (1997). [10] E.G Thorsteinsson, The Nitrogen Discharge. A Global (volume averaged) Model Study, Electrical and Computer Engineering, University of Iceland, October 2008. [11] N St J Braithwaite, "Introduction to gas discharges", Plasma Sources Sci. Technol. 9 (2000) 517-527 [12] C. H. Kruger, Christophe O. Laux, Lan Yu, Denis M. Packan, Laurent Pierrot "Nonequilibrium discharges in air and nitrogen plasmas at atmospheric pressure," Pure Applied Chemical., 74(3)(2002)337-347.