On the circularly polarized luminescence of individual triplet sublevels
Authors/Creators
- 1. University of Pennsylvania
- 2. University of Pittsburgh
Description
We discuss the possibility of using circularly polarized luminescence (CPL) as a tool to probe individual triplet spin sublevels that are populated nonadiabatically following photoexcitation. This study is motivated by a mechanism pro- posed for chirality-induced spin selectivity in which coupled electronic-nuclear dynamics may lead to a non-statistical population of the three triplet sublevels in chiral systems. We find that low-temperature CPL should aid in quantifying the exact spin state/s populated through coupled electronic-nuclear motion in chiral molecules.
Notes (English)
This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in J. Chem. Phys. 159, 134304 (2023) and may be found at https://doi.org/10.1063/5.0159932
Table of contents
Accepted Manuscript and dataset.