Published April 5, 2023 | Version v1
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Data for: "A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes"

Creators

  • 1. RPFL
  • 2. EPFL
  • 3. Institut National des Sciences Appliquées

Description

Low valent uranium can be stabilized via an unprecedented mechanism involving intramolecular ligand migration:the two-and three-electron reduction of the oxo-bridgedU(IV)/U(IV)complex,[{(Ph3SiO)3(DME)U}2(O)], yields formal “U(II)”/U(IV) and “U(I)”/U(IV) complexes,via ligand migration and formation of uranium-arene δ-bond interactions,that can transfer up to threeelectrons tosubstrates by restoring the original ligand arrangement.

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Additional details

Related works

Is supplemented by
10.1002/anie.202304051 (DOI)

Funding

DESIGN OF MULTIMETALLIC COMPLEXES OF F-ELEMENTS IN UNUSUAL OXIDATION STATES: ACTIVATION AND FUNCTIONALIZATION OF DINITROGEN AND MAGNETIC PROPERTIES 212723
Swiss National Science Foundation

References