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Published November 25, 2022 | Version v1
Dataset Open

Supporting Information for the Journal Article "High-throughput ab initio reaction mechanism exploration in the cloud with automated multi-reference treatment"

  • 1. Laboratory of Physical Chemistry, ETH Zurich
  • 2. Microsoft Quantum
  • 3. Department of Chemistry, Technical University Munich
  • 4. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory

Description

This dataset contains the supporting information for the journal article "High-throughput ab initio reaction mechanism exploration in the cloud with automated multi-reference treatment". It consists of two files:

  • "structures.json", containing 3335 unique structures found in the exploration, and
  • "energies.json", containing 2227 elementary steps and its energies found in the exploration

Due to the nature of exploration, certain structures can be explored from multiple elementary steps. Therefore, duplicated structures are common in the reaction exploration. In "structures.json", we de-duplicated the structures and only list the unique ones. The coordinates (in bohr) and global attributes like spin multiplicity and charge are provided. 

In "energies.json", each "step" represents an elementary step. 1260 of the steps are barrierless, while 967 of the steps have a barrier. The structures keys cited in "lhs", "rhs", and "ts" are before de-duplication. The "id" in each structure key points to the unique, de-duplicated structure in "structures.json".

Files

energies.json

Files (13.3 MB)

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md5:5ae10cd34192b96b5b3664570594091b
2.7 MB Preview Download
md5:98009ceeb3de45510313eaa7c4468eeb
10.7 MB Preview Download