Published May 19, 2016
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Cooperative High-Temperature Spin Crossover Accompanied by a Highly Anisotropic Structural Distortion
Description
A new 3D cyanoheterometallic framework, [Fe(pz){Au(CN)2}2], displays a highly cooperative spin crossover at elevated temperatures. The low-spin-to-high-spin transition induces a drastic structural distortion that involves a large one-directional expansion (10.6 %) and contraction (9.6 %) of the lattice.
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