Published April 4, 2022 | Version v1
Journal article Restricted

Functionalized metallic transition metal dichalcogenide (TaS2) for nanocomposite membranes in direct methanol fuel cells

  • 1. Graphene Labs, Istituto Italiano di Tecnologia, via Morego 30, 16163 Genova, Italy
  • 2. BeDimensional S.p.A, Lungotorrente Secca, 30R 16163 Genoa, Italy
  • 3. High-Temperature Fuel Cell Research Department, Vali-e-Asr University of Rafsanjan, 7718897111 Rafsanjan, Iran
  • 4. Department of Applied Chemistry, Faculty of Chemistry, Urmia University, 5756151818 Urmia, Iran
  • 5. Smart Materials, Istituto Italiano di Tecnologia, via Morego 30, 16163 Genova, Italy
  • 6. Materials Characterization Facility, Istituto Italiano di Tecnologia, via Morego 30, 16163 Genova, Italy
  • 7. Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
  • 8. Department of Materials Science and Engineering, Uppsala University, Box 534, 751 03 Uppsala, Sweden


In this work, we designed a novel nanocomposite proton-exchange membrane (PEM) based on sulfonated poly(ether ether ketone) (SPEEK) and tantalum disulfide functionalized with terminal sulfonate groups (S-TaS2). The PEMs are prepared through a solution-casting method and exploited in direct methanol fuel cells (DMFCs). Two-dimensional S-TaS2 nanoflakes were prepared as a functional additive to produce the novel nanocomposite membrane for DMFCs due to their potential as a fuel barrier and an excellent proton conductor. To optimize the degree of sulfonation (DS) of SPEEK and the weight percentage (wt%) of S-TaS2 nanoflakes in PEMs, we used the central composite design of the response surface method. The optimum PEM was obtained for SPEEK DS of 1.9% and a weight fraction (wt%) of S-TaS2 nanoflakes of 70.2%. The optimized membrane shows a water uptake of 45.72%, a membrane swelling of 9.64%, a proton conductivity of 96.24 mS cm−1, a methanol permeability of 2.66 × 10−7 cm2 s−1, and a selectivity of 36.18 × 104 S s cm−3. Moreover, SPEEK/S-TaS2 membranes show superior thermal and chemical stabilities compared to those of pristine SPEEK. The DMFC fabricated with the SPEEK/S-TaS2 membrane has reached the maximum power densities of 64.55 mW cm−2 and 161.18 mW cm−2 at 30 °C and 80 °C, respectively, which are ∼78% higher than the values obtained with the pristine SPEEK membrane. Our results demonstrate that SPEEK/S-TaS2 membranes have a great potential for DMFC applications.



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GrapheneCore2 – Graphene Flagship Core Project 2 785219
European Commission
ULTIMATE – Bottom-Up generation of atomicalLy precise syntheTIc 2D MATerials for high performance in energy and Electronic applications – A multi-site innovative training action 813036
European Commission