Metal Chloride-Phosphorus Chloride--Alkyl Chloride Complexes : Reactions with Gold(III), Zirconium(IV), Platinum(IV) and Oxouranium(VI) Chlorides

Chemistry Department, Kurukshetra University, Kurukshetra-132 119
Manuscript received 18 August 1981, revised 6 September 1982, accepted 3 August 1983
The reactions of anhydrous gold(III), zircooium(IV), platioum(lV) and oxouranium(
Vl) chlorides with trichloro and phenyl dichloro phosphioes in presence of alkylating
agents such as t-butyl chloride, t-amyl chloride, cyclohexyl chloride and trimethyl chloride
have been carried out. Ionic solid products have been obtained and characterised by
elemental analysis, ir and electronic spectra, thermogravimetric analysis, and conductivity
and magnetic susceptibility measurement data.