A Photorobust Mo(0) Complex Mimicking [Os(2,2′-bipyridine)3]2+ and Its Application in Red-to-Blue Upconversion

Data underlying the figures in the publication “A Photorobust Mo(0) Complex Mimicking [Os(2,2′-bipyridine)₃]²⁺ and Its Application in Red-to-Blue Upconversion” published in J. Am. Chem. Soc. 2021, 143, 1651−1663.

Table of contents:

1. Fig 2 Cyclic Voltammetric Studies

   1.1 Fig 2a CV_THF_200mVs-1

   1.2 Fig 2b CV_THF_Scan Rates

2. Fig 3 UV-Vis and Excitation Spectra

3. Fig 4 Transient Absorption Data

   3.1 Transient Absorption Data in Toluene

   3.2 Transient Absorption Data in Cyclohexane

   3.3 Transient Absorption Data in THF

4. Fig 5 Temperature Dependent Luminescence Lifetime

5. Fig 6 and Fig 9 Photostability Studies

6. Fig 7 Kinetic Photo Luminescence Decay

7. Fig 8 Delayed Fluorescence Spectra at Various Power Densities

   7.1 UC_powerDep_2_5mM_5xBE

   7.2 UC_powerDep_10mM_5xBE

   7.3 UC_powerDep_10mM_woutBE

   7.4 UC_powerDep_20mM_woutBE

   7.5 UC_powerDep_50mM_woutBE

8. Fig 11 1H-NMR Data for the Isomerization Experiments

   8.1 control_ini Sample Without DPA prior Irradiation

   8.2 control_on Sample Without DPA Overnight

   8.3 UC_ini Reaction Mixture prior Irradiation

   8.4 UC_on Reaction Mixture Overnight