Published March 18, 2021 | Version v1

Development of computational methods for estimation of current efficiency and cell voltage in a Chlor-alkali membrane cell

  • 1. ROR icon Sechenov University
  • 2. ROR icon Tarbiat Modares University
  • 3. ROR icon Ton Duc Thang University
  • 4. ROR icon Petroleum University of Technology

Description

This work presents proposing two artificial intelligence methods including Least squares support vector machine (LSSVM) and Adaptive neuro fuzzy inference system (ANFIS) for the prediction of caustic current efficiency (CCE) and cell voltage as a function of pH, current density, brine concentration, electrolyte velocity, operating temperature, and run time. The predictions of LSSVM and ANFIS models were evaluated by the experimental values of this process graphically and statistically. The overall R-squared values of LSSVM and ANFIS for prediction of CCE were 0.999 and 0.972, respectively. On the other hand, these values for cell voltage prediction were 1 and 0.998. According to the CCE and cell voltage predictions results, LSSVM algorithm has great performance in prediction of chlor-alkali membrane cell processes. Furthermore, artificial intelligence methods can have wide use in electrolytic processes to enhance power consumption.

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References

  • Abdolbaghi, S., A. Mohamadnazar, M. Hasanipanah, and A. Barati-Harooni. 2020. 'Comparison between a soft computing model and thermodynamic models for prediction of phase equilibria in binary mixtures containing 1-alkanol, n-alkane, and CO2ʹ, Fluid Phase Equilibria, Vol. 503, 112307, Elsevier, Netherlands.
  • Ashrafizadeh, S. N., F. Mohammadi, A. Sattari, and N. Shojaikaveh. 2010. 'Prediction of Cell Voltage and Chlorine Current Efficiency of Aqueous HCl Electrolysis Utilizing an Oxygen Reducing Cathode Based on Artificial Neural Network'. ECS Transactions 25 (33):27–42. doi:10.1149/1.3334789.
  • Baghban, A., M. Bahadori, A. S. Lemraski, and A. Bahadori. 2016. 'Prediction of solubility of ammonia in liquid electrolytes using least square support vector machines'. Ain Shams Engineering Journal 9:1303–1312.
  • Barati-Harooni, A., A. Najafi-Marghmaleki, M. Arabloo, and A. H. Mohammadi. 2016. 'An accurate CSA-LSSVM model for estimation of densities of ionic liquids'. Journal of Molecular Liquids 224:954–64. doi:10.1016/j.molliq.2016.10.027.
  • Barati-Harooni, A., A. Najafi-Marghmaleki, S.-A. Hoseinpour, A. Tatar, A. Karkevandi-Talkhooncheh, A. Hemmati-Sarapardeh, and A. H. Mohammadi. 2019. 'Estimation of minimum miscibility pressure (MMP) in enhanced oil recovery (EOR) process by N2 flooding using different computational schemes'. Fuel 235:1455–74. doi:10.1016/j.fuel.2018.08.066.
  • Barati-Harooni, A., A. Najafi-Marghmaleki, and A. H. Mohammadi. 2016. 'ANFIS modeling of ionic liquids densities'. Journal of Molecular Liquids 224:965–75. doi:10.1016/j.molliq.2016.10.050.
  • Bemani, A., A. Baghban, A. H. Mohammadi, and P. Ø. Andersen. 2020. 'Estimation of adsorption capacity of CO2, CH4, and their binary mixtures in Quidam shale using LSSVM: Application in CO2 enhanced shale gas recovery and CO2 storage'. Journal of Natural Gas Science and Engineering 76:103204. doi:10.1016/j.jngse.2020.103204.
  • Cao, B., J. Zhao, Z. Lv, Y. Gu, P. Yang, and S. K. Halgamuge. 2020. 'Multiobjective Evolution of Fuzzy Rough Neural Network via Distributed Parallelism for Stock Prediction'. IEEE Transactions on Fuzzy Systems 28 (5):939–52. doi:10.1109/TFUZZ.2020.2972207.
  • Chao, L., K. Zhang, Z. Li, Y. Zhu, J. Wang, and Z. Yu. 2018. 'Geographically weighted regression based methods for merging satellite and gauge precipitation'. Journal of Hydrology 558:275–89. doi:10.1016/j.jhydrol.2018.01.042.
  • Chen, H., A. Chen, L. Xu, H. Xie, H. Qiao, Q. Lin, and K. Cai. 2020. 'A deep learning CNN architecture applied in smart near-infrared analysis of water pollution for agricultural irrigation resources'. Agricultural Water Management 240:106303. doi:10.1016/j.agwat.2020.106303.
  • Chen, S., M. K. Hassanzadeh-Aghdam, and R. Ansari. 2018. An analytical model for elastic modulus calculation of SiC whisker-reinforced hybrid metal matrix nanocomposite containing SiC nanoparticles. Journal of Alloys and Compounds 767:632–41. doi:10.1016/j.jallcom.2018.07.102.
  • Chikhi, M., M. Rakib, P. Viers, S. Laborie, A. Hita, and G. Durand. 2002. 'Current distribution in a chlor-alkali membrane cell: Experimental study and modeling'. Desalination 149 (1–3):375–81. doi:10.1016/S0011-9164(02)00834-2.
  • Dias, A. C., M. J. Pereira, L. Brandao, P. Araujo, and A. Mendes. 2010. 'Characterization of the Chlor-Alkali Membrane Process by EIS I. Ohmic Resistance'. Journal of the Electrochemical Society 157 (5):E75–E81. doi:10.1149/1.3328487.
  • Ershadnia, R., M. A. Amooie, R. Shams, S. Hajirezaie, Y. Liu, S. Jamshidi, and M. R. Soltanian. 2020. 'Non-Newtonian fluid flow dynamics in rotating annular media: Physics-based and data-driven modeling'. Journal of Petroleum Science and Engineering 185:106641. doi:10.1016/j.petrol.2019.106641.
  • Jalali, A. A., F. Mohammadi, and S. N. Ashrafizadeh. 2009. 'Effects of process conditions on cell voltage, current efficiency and voltage balance of a chlor-alkali membrane cell'. Desalination 237 (1–3):126–39. doi:10.1016/j.desal.2007.11.056.
  • Kaveh, N. S., S. N. Ashrafizadeh, and F. Mohammadi. 2008. 'Development of an artificial neural network model for prediction of cell voltage and current efficiency in a chlor-alkali membrane cell'. Chemical Engineering Research and Design 25 (5):461–72. doi:10.1016/j.cherd.2007.12.009.
  • Kaveh, N. S., F. Mohammadi, and S. N. Ashrafizadeh. 2009. 'Prediction of cell voltage and current efficiency in a lab scale chlor-alkali membrane cell based on support vector machines'. Chemical Engineering Journal 147 (2–3):161–72. doi:10.1016/j.cej.2008.06.030.
  • Keybondorian, E., B. S. Soulgani, and A. Bemani. 2018. 'Application of ANFIS-GA algorithm for forecasting oil flocculated asphaltene weight percentage in different operation conditions'. Petroleum Science and Technology 36 (12):862–68. doi:10.1080/10916466.2018.1447960.
  • Keybondorian, E., H. Zanbouri, A. Bemani, and T. Hamule. 2017. 'Estimation of the higher heating value of biomass using proximate analysis'. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects 39 (20):2025–30. doi:10.1080/15567036.2017.1400609.
  • Li, T., M. Xu, C. Zhu, R. Yang, Z. Wang, and Z. Guan. 2019. 'A deep learning approach for multi-frame in-loop filter of HEVC'. IEEE Transactions on Image Processing 28 (11):5663–78. doi:10.1109/TIP.2019.2921877.
  • Malmir, P., M. Suleymani, and A. Bemani. 2018. 'Application of ANFIS-PSO as a novel method to estimate effect of inhibitors on Asphaltene precipitation'. Petroleum Science and Technology 36 (8):597–603. doi:10.1080/10916466.2018.1437637.
  • Mazloom, M. S., F. Rezaei, A. Hemmati-Sarapardeh, M. M. Husein, S. Zendehboudi, and A. Bemani. 2020. 'Artificial Intelligence Based Methods for Asphaltenes Adsorption by Nanocomposites: Application of Group Method of Data Handling, Least Squares Support Vector Machine, and Artificial Neural Networks'. Nanomaterials 10 (5):890. doi:10.3390/nano10050890.
  • Mir, M., M. Kamyab, M. J. Lariche, A. Bemani, and A. Baghban. 2018. 'Applying ANFIS-PSO algorithm as a novel accurate approach for prediction of gas density'. Petroleum Science and Technology 36 (12):820–26. doi:10.1080/10916466.2018.1446176.
  • Muthumeenal, A. S. A. S. M., M. Sri Abirami Saraswathi, D. Rana, A. Nagendran, and S. Sridhar. 2018. "Recent research trends in polymer nanocomposite proton exchange membranes for electrochemical energy conversion and storage devices.". In Membrane Technology: Sustainable Solutions in Water, Health,Energy and Environmental Sectors: Taylor & Francis/CRC Press Boca Raton, FL, 17, pp. 351–374. doi:10.1201/9781315105666.
  • Najafi-Marghmaleki, A., A. Tatar, A. Barati-Harooni, M. Arabloo, S. Rafiee-Taghanaki, and A. H. Mohammadi. 2018. 'Reliable modeling of constant volume depletion (CVD) behaviors in gas condensate reservoirs'. Fuel 231:146–56.
  • Quan, Q., Z. Hao, H. Xifeng, and L. Jingchun. 2020. 'Research on water temperature prediction based on improved support vector regression'. Neural Computing and Applications 32:1–10.
  • Rana, D., T. Matsuura, and S. M. Javaid Zaidi. 2009. Research and development on polymeric membranes for fuel cells: An overview, In Polymer Membranes for Fuel Cells, 550, Springer: Boston.
  • Shi, K., J. Wang, Y. Tang, and S. Zhong. 2020. 'Reliable asynchronous sampled-data filtering of T–S fuzzy uncertain delayed neural networks with stochastic switched topologies'. Fuzzy Sets and Systems 381:1–25.
  • Shojaikaveh, N., S. N. Ashrafizadeh, F. Mohammadi, and A. Amerighasrodashti. 2010. 'Optimization of Predicted Cell Voltage & Caustic Current Efficiency in a Chlor-Alkali Membrane Cell with Application of Genetic Algorithm'. ECS Transactions 25:43–56.
  • Tatar, A., A. Barati-Harooni, A. Najafi-Marghmaleki, and A. Bahadori. 2017. 'Accurate prediction of CO2 solubility in eutectic mixture of levulinic acid (or furfuryl alcohol) and choline chloride'. International Journal of Greenhouse Gas Control 58:212–22.
  • Tripathi, B. P., and V. K. Shahi. 2011. 'Organic–inorganic nanocomposite polymer electrolyte membranes for fuel cell applications'. Progress in Polymer Science 36:945–79.
  • Yang, S., B. Deng, J. Wang, L. Huiyan, L. Meili, Y. Che, X. Wei, and K. A. Loparo. 2019. 'Scalable digital neuromorphic architecture for large-scale biophysically meaningful neural network with multi-compartment neurons'. IEEE Transactions on Neural Networks and Learning Systems 31:148–62.
  • Zhu, Q. 2019. 'Research on Road Traffic Situation Awareness System Based on Image Big Data'. IEEE Intelligent Systems 35:18–26.