Published December 5, 2025 | Version v1

Investigation of Optical Band Gap and Physical Properties of Nd3+-doped Borate Glasses

  • 1. Department of Physics, School of Sciences, IFTM University, Moradabad, U.P-244102, India
  • 2. Department of Physics, S. B. S. govt. P. G. College, Rudrapur-263153, India
  • 3. Department of Chemistry, School of Sciences, IFTM University, Moradabad, U.P-244102, India

Description

Nd3+- doped cadmium borate glasses were prepared and characterized optically. The oscillator strengths and Judd-Ofelt parameters for the glass containing 0.1, 0.3 and 0.5 wt% of Nd2¬O3 were computed. Density, refractive index and optical absorption spectra were measured. The values of Judd- Ofelt parameters suggested an increase in the degree of asymmetry the local ligand field at Nd3+ sites. The optical band gap energy and physical parameters was calculated for all glass samples.

Files

13. Jitendra Pal Singh.pdf

Files (460.1 kB)

Name Size Download all
md5:35fb92d94c9b74a4a0d8b6d4395a4a4c
460.1 kB Preview Download

Additional details

References

  • 1. A. Kamniskii, Laser Crystals, second ed. Springer, Berlin pp. 252 (1990). 2. E. Pacoraro, J. A. Sampaio, L. A. O. Nunes, S. Gama and M. L. Baesso, J. Non-Cryst. Solids 77 (2000) 3. B. Karthikeyan, R. Philip, S. Mohan, Optics Commun. 246, 153 (2005) 4. S.E. Stokowski, R.A. Saroyan, and M.J. Weber, Nd-Doped Laser Glass Spectroscopy and Physical properties, Lawrence Livermore national laboratory Report m-095 (1981). 5. S. Thomas, Sk.N.Rasool, M.Rathaiah, V.Venkatramu, C. Joseph, N.V. Unnikrishnan, J.Non-Cryst. Solids, 376,106 (2013). 6. Y.K. Sharma, S.S.L. Surana, R.P. Dubedi, V.Joshi, Mat. Sci. Engg. B, 119, 131 (2005) 7. Y.K. Sharma, S.S.L. Surana, R.K.Singh, R.P. Dubedi, Optical materials, 29, 598 (2007). 8. V.N. Rai, B.N. Raja Sekhar, P.Tiwari, R.J. Kshirsagar and S.K.Deb, J.Non. Cryst. Solids, 357, 3757 (2011). 9. E. Snitzer, Phys. Rev. Lett., 7, 444 (1961) 10. K. A. Gshneidner, Jr., L. R. Eyring, Handbook on the Physics and Chemistry of Rare earths, Elesvies Amasterdom, Lausanne, New York, Oxford, Shannon, Singapore, Tokyo (1998) 11. Y.K. Sharma, S.S.L. Surama, R.K. Singh, J. Rare Earth, 27, 773 (2009) 12. Y. K. Sharma, S. C. Mathur, D. C. Dube, J. Mat. Sci. Lett., 15 , 1054 (1996) 13. R. P. Joshi, H. N. B. Garhwal University, Srinagar, Uttarakhand, Ph D thesis, (2009) 14. Beena Bhatia, Vishal Parihar, Sanjay Singh, A. S. Verma, American Journal of Condensed Matter Physics, 3(3),80(2013) 15. S.P. Tandon, S.S.L. Surana, K. Tandon, M.P. Bhutra, K.K. Sule, R.C. Govil, N.B. Bishoni, and Y.K. Sharma, Optical Studies of Rare Earth Lasing materials Suitable for Higher Repetitive Rates with Special Reference to Defence Applications, Report on AR and DB project No. 393, India (1989). 16. C. K. Jorgensen, J. Inorg, Nucl. Chem., 1, 301 (1955) 17. B. R. Judd, Phys. Rev., 127, 750(1960) 18. G. S. Ofelt, J. Chem. Phys., 37,511(1962) 19. C. H. Goublen, Method of Stastical Analysis, Asia Publishing house Bombay, Chep. 8, 134(1964)