Published September 4, 2025 | Version Version 1

Polymer-assisted Crystallization and Defect Passivation in Planar Wide Bandgap FAPbBr3 Perovskite Solar Cells

  • 1. Czech Technical University in Prague
  • 2. University of Chemistry and Technology

Description

We demonstrate a polymer-assisted strategy to improve FAPbBr3 wide bandgap perovskite solar cells by incorporating poly(methyl methacrylate) (PMMA) into the antisolvent. PMMA passivates defects via coordination with Pb2+ ions, enhancing crystallinity, reducing sub-bandgap states, and suppressing non-radiative recombination. This results in improved film quality, a Voc increase of over 100 mV, enhanced efficiency, and greater device stability.

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Additional details

Related works

Is derived from
Dataset: 10.5281/zenodo.15490167 (DOI)
Is new version of
Preprint: 10.5281/zenodo.15490265 (DOI)

Funding

Ministry of Education Youth and Sports
The Energy Conversion and Storage CZ.02.01.01/00/22_008/0004617

Dates

Submitted
2025-05-21
Sent to peer review process