Published August 29, 2023 | Version v1
Journal article Open

One-Pot Synthesis of Stable CsPbBr3@CsPb2Br5 Core–Shell Heteronanocrystals with Controlled Permeability to Halide Ions

  • 1. ROR icon Universitat de València
  • 2. Instituto de Nanociencia y Materiales de Aragón (INMA),

Description

A simple one-pot synthetic strategy based on the hot injection methodology was adapted to prepare (photo)stable and green emissive colloidal CsPbBr3@CsPb2Br5 core@shell heteronanocrystals (HNCs). The photoactive core, specifically CsPbBr3 ternary metal halide nanocrystals, was homogeneously covered with an ultrathin CsPb2Br5 shell (ca. 2 nm), which confers them with long-term stability and a higher photoluminescence quantum yield. Astonishingly, this heterostructure enabled controlled halide exchange to yield unprecedented CsPbCl3@CsPb2Cl5 and CsPbI3@CsPb2I5 HNCs.

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rosa-pardo-et-al-2023-one-pot-synthesis-of-stable-cspbbr3-cspb2br5-core-shell-heteronanocrystals-with-controlled (1).pdf

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