Published November 6, 2015
| Version v1
Figure
Open
Fig. 5 in Identification of b-hydroxy fatty acid esters and primary, secondary-alkanediol esters in cuticular waxes of the moss Funaria hygrometrica
Authors/Creators
- 1. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada
Description
Fig. 5. Synthesis of 7-hydroxytriacontyl palmitate. Tetracosanal (10), as obtained from tetracosanoic acid through two redox steps, was added to the Grignard reagent 7a obtained from THP-protected, brominated 1,6-hexanediol (5). An acidic workup afforded 1,7-triacontanediol (11), which was then esterified with palmitoyl chloride to form 7-hydroxytriacontyl palmitate (12). Compounds in parentheses were not isolated, but used directly in the following step. Yields and procedural details are given in the Experimental section. Abbreviations: LAH = lithium aluminum hydride, DMAP = 4-dimethylaminopyridine.
Notes
Published as part of Busta, Lucas, Budke, Jessica M. & Jetter, Reinhard, 2016, Identification of b-hydroxy fatty acid esters and primary, secondary-alkanediol esters in cuticular waxes of the moss Funaria hygrometrica, pp. 38-49 in Phytochemistry 121 on page 44, DOI: 10.1016/j.phytochem.2015.10.007, http://zenodo.org/record/10485687
Files
figure.png
Files
(151.7 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:8861744120194692c1e51ffdd77182b4
|
151.7 kB | Preview Download |
Linked records
Additional details
Related works
- Is part of
- Journal article: 10.1016/j.phytochem.2015.10.007 (DOI)
- Journal article: urn:lsid:plazi.org:pub:FF98FFACFF93D053945B8B1BFFE4FF96 (LSID)
- Journal article: https://zenodo.org/record/10485687 (URL)