Published September 30, 2018 | Version v1
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Fig. 9 in Glucosinolate turnover in Brassicales species to an oxazolidin-2-one, formed via the 2-thione and without formation of thioamide

  • 1. * & Copenhagen Plant Science Center and Department of Plant and Environmental Sciences, University of Copenhagen, Thorvaldsensvej 40, 1871 Frederiksberg

Description

Fig. 9. Evidence for conversion of spiked (S)-5-ethyl-5-methylOAT (9) into 5-ethyl-5-methylOAO (10) by a heat-sensitive catalyst in a B. vulgaris leaf homogenate. A-D, Total ion chromatograms; E-H, extracted ion chromatograms for specific detection of the OAO product 10. AþE, extract of native homogenate after incubation (2 h) with spike of 9 dissolved in water; BþF, control extract of homogenate spiked with water; CþG, control similar to AþE but homogenate briefly heated before spike; DþH, control consisting of the same spike as in A and C but incubated in acetate buffer (pH 5, 2 h) in parallel.

Notes

Published as part of Agerbirk, Niels, Matthes, Annemarie, Erthmann, Pernille Ø., Ugolini, Luisa, Cinti, Susanna, Lazaridi, Eleni, Nuzillard, Jean-Marc, Müller, Caroline, Bak, SØren, Rollin, Patrick & Lazzeri, Luca, 2018, Glucosinolate turnover in Brassicales species to an oxazolidin-2-one, formed via the 2-thione and without formation of thioamide, pp. 79-93 in Phytochemistry 153 on page 87, DOI: 10.1016/j.phytochem.2018.05.006, http://zenodo.org/record/10483781

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Journal article: 10.1016/j.phytochem.2018.05.006 (DOI)
Journal article: urn:lsid:plazi.org:pub:FFF64036FFCFF62EFF94FFECFF9BFF84 (LSID)
Journal article: https://zenodo.org/record/10483781 (URL)