Published December 4, 2013
| Version v1
Journal article
Open
Rationale for the sluggish oxidative addition of aryl halides to Au(I)
Authors/Creators
- 1. Institute of Chemical Research of Catalonia (ICIQ)
Description
The oxidative addition of Csp2–Br or Csp2–I bonds to gold(I) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(III) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish.
Files
c3cc48914k.pdf
Files
(1.3 MB)
| Name | Size | Download all |
|---|---|---|
|
md5:c6d60157d154c8cada74c3ffb7518086
|
1.3 MB | Preview Download |