Journal article Open Access

Anion-induced dimerization of 5-fold symmetric cyanostars in 3D crystalline solids and 2D self-assembled crystals

Hirsch, Brandon E.; Lee, Semin; Qiao, Bo; Chen, Chun-Hsing; McDonald, Kevin P.; Tait, Steven L.; Flood, Amar H.

Anions stabilize stacking of C5-symmetric macrocycles, called cyanostars, into dimers in solution and herein we demonstrate this stacking in solid-state crystals. We further show that this guest binding can be applied as a route to bilayer growth at the solution– graphite interface.

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