Published November 11, 2022 | Version v1

Pure water as a mobile phase in liquid chromatography techniques

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  • 1. Principal

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Liquid chromatography is a technique that is gaining increasing interest and application, for example in the pharmaceutical industry. At the same time as the increase in the number of analyses performed, the amount of organic waste produced while working with high-performance liquid chromatography (HPLC) apparatus is growing. Therefore, new methods and materials are being searched for to achieve the socalled “green” chromatography. In the following review we describe one of them, specifically the replacement of harmful organic solvents such as acetonitrile, methanol or isopropanol, with pure water used as the sole component of the mobile phase. In order to achieve a single component mobile phase, different methods or materials are used: the use of elevated temperature, the selection of new stationary phases, the utilization of changes in the properties of the stationary phase while using a highly polar eluent.

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References

  • 1. Y. Yang, Z. Strickland, B. Kapalavavi, R. Marple, C. Gamsky, Industrial application of green chromatographydI. Separation and analysis of niacinamide in skincare creams using pure water as the mobile phase, Talanta 84 (2011) 169–174. https://doi.org/10.1016/J.TALANTA .2010.12.044. 2. Z. Safaei, S. Bocian, B. Buszewski, Green chromatography-carbon footprint of columns packed with core-shell materials, RSC Adv. 4 (2014) 53915e53920. https://doi.org/10.1039/c4ra11456f. Volume 8 Issue 6 @ 2022 IJIRCT | ISSN: 2454-5988 IJIRCT2206006 International Journal of Innovative Research and Creative Technology (www.ijirct.org) 42 3. V. Gonz alez-Ruiz, A.G. Leon, A.I. Olives, M.A. Martín, J.C. Men endez, Eco- friendly liquid chromatographic separations based on the use of cyclodextrins as mobile phase additives, Green Chem. 13 (2011) 115e126. https://doi.org/10.1039/c0gc00456a. 4. D. Raynie, The greening of the chromatography laboratory, LC GC Eur. 24 (2011) 78e91. 5. B.P. Sandra, G. Vanhoenacker, F. David, K. Sandra, A. Pereira, Green chromatography (part 1 ): introduction and liquid chromatography, LC GC Eur. (2011) 1e21. 6. D. Satínský, I. Brabcov a, A. Marouskova, P. Chocholou s, P. Solich, Green chromatography separation of analytes of greatly differing properties using a polyethylene glycol stationary phase and a low-toxic water-based mobile phase, Anal. Bioanal. Chem. 405 (2013) 6105e6115. https://doi.org/10.1007/ s00216-013-7003-1. 7. K. Chen, F. Lynen, M. De Beer, L. Hitzel, P. Ferguson, M. Hanna-Brown, P. Sandra, Selectivity optimization in green chromatography by gradient stationary phase optimized selectivity liquid chromatography, J. Chromatogr. A. 1217 (2010) 7222-7230. https://doi.org/10.1016/J.CHROMA. 2010.09.029. 8. M. Furusawa, K. Kishida, Determining sulfamethazine in pork using HPLC with a 100% water mobile phase, LC GC N Am. 22 (2004) 1092–1096. 9. N. Furusawa, E. Tsumatani, Green HPLC with 100% water eluent for analysing melamine in milk, LC GC Eur. 25 (2012) 292–298. 10. Y. Yang, Subcritical water chromatography: a green approach to hightemperature liquid chromatography, J. Sep. Sci. (2007). https://doi.org/ 10.1002/jssc.200700008. 11. R.M. Smith, Superheated water chromatography e a green technology for the future, J. Chromatogr. A. 1184 (2008) 441–455. https://doi.org/10.1016/ j.chroma.2007.07.002. 12. A.S. Pereira, A.J. Giron, E. Admasu, P. Sandra, Green hydrophilic interaction chromatography using ethanolwater-carbon dioxide mixtures, J. Sep. Sci. 33 (2010) 834–837. https://doi.org/10.1002/jssc.200900791. 13. C.J. Welch, N. Wu, M. Biba, R. Hartman, T. Brkovic, X. Gong, R. Helmy, W. Schafer, J. Cuff, Z. Pirzada, L. Zhou, Greening analytical chromatography, TrAC e Trends Anal. Chem. 29 (2010) 667–680. https://doi.org/10.1016/ j.trac.2010.03.008. 14. R.E. Majors, Current trends in HPLC column usage, LC GC N Am. 30 (2012), 20,22,24,26,28,30-32,34. 15. T. Greibrokk, T. Andersen, High-temperature liquid chromatography, J. Chromatogr. A. 1000 (2003) 743e755. https://doi.org/10.1016/S0021- 9673(02)01963-5. 16. S. Heinisch, J.L. Rocca, Sense and nonsense of high-temperature liquid chromatography, J. Chromatogr. A. 1216 (2009) 642–658. https://doi.org/ 10.1016/j.chroma.2008.11.079. 17. C.V. McNeff, B. Yan, D.R. Stoll, R.A. Henry, Practice and theory of high temperature liquid chromatography, J. Sep. Sci. 30 (2007) 1672–1685. https:// doi.org/10.1002/jssc.200600526. 18. D. Guillarme, S. Heinisch, Detection modes with high temperature liquid chromatography e a review, Sep. Purif. Rev. 34 (2005) 181–216. https:// doi.org/10.1080/15422110500323055. 19. G. Vanhoenacker, P. Sandra, Elevated temperature and temperature programming in conventional liquid chromatography e fundamentals and applications, J. Sep. Sci. 29 (2006) 1822e1835. https://doi.org/10.1002/ jssc.200600160. 20. J.W. Dolan, Temperature selectivity in reversed-phase high performance liquid chromatography, J. Chromatogr. A. 965 (2002) 195–205. https:// doi.org/10.1016/S0021-9673(01)01321-8. 21. J.W. Coym, J.G. Dorsey, Superheated water chromatography: a brief review of an emerging technique, Anal. Lett. 37 (2004) 1013e1023. https://doi.org/ 10.1081/AL-120030294. 22. J. Bowermaster, H.M. McNair, Temperature programmed microbore HPLCdpart I, J. Chromatogr. Sci. 22 (1984) 165–170. https://doi.org/ 10.1093/chromsci/22.4.165. 23. Michelle Hong Chen, C. Horv ath, Temperature programming and gradient elution in reversed-phase chromatography with packed capillary columns, J. Chromatogr. A. 788 (1997) 51–61. https://doi.org/10.1016/S0021-9673(97) 00715-2. 24. J.V. Tran, P. Molander, T. Greibrokk, E. Lundanes, Temperature effects on retention in reversed phase liquid chromatography, J. Sep. Sci. 24 (2001) 930–940. https://doi.org/10.1002/1615-9314(20011201)24:123.0.CO;2- 2. 25. T. Kondo, Y. Yang, Comparison of elution strength, column efficiency, and peak symmetry in subcritical water chromatography and traditional reversed-phase liquid chromatography, Anal. Chim. Acta 494 (2003) 157–166. https://doi.org/10.1016/S0003-2670(03)00865-1. 26. D. Guillarme, S. Heinisch, J.Y. Gauvrit, P. Lanteri, J.L. Rocca, Optimization of the coupling of high-temperature liquid chromatography and flame ionization detection: application to the separations of alcohols, J. Chromatogr. A. 1078 (2005) 22–27. https://doi.org/10.1016/j.chroma.2005.04.092. 27. K. Hartonen, M.L. Riekkola, Liquid chromatography at elevated temperatures with pure water as the mobile phase, TrAC e Trends Anal. Chem. 27 (2008) 1e14. https://doi.org/10.1016/j.trac.2007.10.010. Volume 8 Issue 6 @ 2022 IJIRCT | ISSN: 2454-5988 IJIRCT2206006 International Journal of Innovative Research and Creative Technology (www.ijirct.org) 43 28. S.B. Hawthorne, Y. Yang, D.J. Miller, Extraction of organic pollutants from environmental solids with sub- and supercritical water, Anal. Chem. 66 (1994) 2912–2920. https://doi.org/10.1021/ac00090a019. 29. R.M. Smith, R.J. Burgess, Superheated water e a clean eluent for reversedphase high-performance liquid chromatography, Anal. Commun. 33 (1996) 327–329. https://doi.org/10.1039/AC9963300327. 30. J.D. Thompson, P.W. Carr, A study of the critical criteria for analyte stability in high-temperature liquid chromatography, Anal. Chem. 74 (2002) 1017e1023. https://doi.org/10.1021/ac010917w.