Published May 15, 2023 | Version 1

Dataset for Unified acidity of liquid chromatography mobile phases with methanol and acetonitrile

  • 1. University of Tartu, Institute of Chemistry

Contributors

  • 1. University of Tartu, Institute of Chemistry

Description

Dataset for article "Unified acidity of liquid chromatography mobile phases with methanol and acetonitrile".

Here we report the data of 78 reversed-phase liquid chromatography-mass spectrometry mobile phases that were determined by potential differences in a symmetric cell with two glass electrode half-cells and almost ideal ionic liquid triethylamylammonium bis((trifluoromethyl)sulfonyl)imide [N2225][NTf2] salt bridge with multiple overlapping measurements. In addition, for 45 of these mobile phases, the potential difference between a glass and a double junction reference electrode were measured.

Procedures used with Keysight B2987A Electrometer are given in dx.doi.org/10.17504/protocols.io.n92ld9dj8g5b/v2  and dx.doi.org/10.17504/protocols.io.byh2pt8e. For other instruments, the procedures differ by software and instrument connections.

 

Notes

This research was funded from the EMPIR programme (project 17FUN09 "UnipHied") co-financed by the Participating States and from the European Union's Horizon 2020 research and innovation programme; by the EU through the European Regional Development Fund under project TK141 "Advanced materials and high-technology devices for energy recuperation systems" (2014-2020.4.01.15-0011) and by the Estonian Research Council grant (PRG690). This work was carried out using the instrumentation at the Estonian Center of Analytical Chemistry (TT4, www.akki.ee).

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