Published November 15, 2021
| Version v1
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Ga–Ni supported catalytically active liquid metal solutions (SCALMS) for selective ethylene oligomerization
Creators
- 1. Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Lehrstuhl für Chemische Reaktionstechnik (CRT), Egerlandstr. 3, 91058 Erlangen, Germany
- 2. Forschungszentrum Jülich GmbH, Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy (IEK 11), Egerlandstr. 3, 91058 Erlangen, Germany
Description
Non-precious metal supported catalytically active liquid metal solutions exhibit attractive performance in ethylene oligomerization. It is found for the Ga–Ni system on silica that the performance depends strongly on the applied Ga/Ni ratio. Ga-rich systems forming liquid alloys exhibit a far higher Ni-based catalytic activity than solid intermetallic compounds or Ni nanoparticles.
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