3D-Printed PLA/PEO Blend as Biodegradable Substrate Coating with CoCl2 for Colorimetric Humidity Detection
- 1. Department of Chemistry and Center for Innovation in Chemistry, Graduate School, Chiang Mai University
- 2. Science and Technology Research Institute, Chiang Mai University
- 3. Department of Chemistry and Center for Innovation in Chemistry,Chiang Mai University
- 4. Department of Chemistry, Faculty of Science, Chiang Mai University
- 5. National Security and Dual-Use Technology Center, National/Science and Technology Development Agency Thailand
- 6. Department of Chemistry, Faculty of Science, Burapha University
- 7. Aston Institute of Materials Research, College of Engineering and Physical Sciences, Aston University
- 8. Department of Chemistry and Center for Innovation in Chemistry, Center of Excellence in Materials Science and Technology, Chiang Mai University
Description
This study aimed to fabricate biodegradable substrate with colorimetric humidity indicator for detective moisture in food packaging. The poor properties of poly(lactic acid) (PLA) were enhanced by melt blending PLA with non-toxic poly(ethylene oxide) PEO at 180 °C. Specifically, three-dimensional (3D) substrates of PLA/PEO blends were fabricated by solvent-cast 3D printing. Furthermore, cobalt chloride (CoCl2) solution was printed onto the substrate with an inkjet printer to serve as a colorimetric humidity sensing indicator. It found that the flexibility and thermal stability of the PLA were improved and the hydrophilicity was increased with an increase in PEO content. Color changes and the sensitivity of this material were confirmed using image analysis and total color difference. The CoCl2 indicator displayed color changes that ranged from blue to pink under ambient conditions (above 60%RH), revealing suitable potential for frozen food packaging material with aim to detect amount of moisture in the packaging.