Published February 27, 2023
| Version v1
Journal article
Open
A Kinetic Approach to the Pyrolysis of Naphthenic Acids
Authors/Creators
- 1. Department of Chemistry, Boğaziçi University, 34342, Istanbul, Turkey
- 2. Turkish Petroleum Refineries Co. (TUPRAŞ) R&D Center, 41790 Korfez, Kocaeli, Turkey
- 3. Department of Chemistry, Boğaziçi University, 34342, Istanbul, Turkey-Université de Reims Champagne-Ardenne, Reims, 51687, France
Description
- Naphthenic acids can be pyrolyzed in the existing refinery/petrochemical furnaces.
- Unimolecular decomposition of carboxylic acids via quantum mechanical tools is studied.
- The effect of ring number/type, chain length, and acidic group location are discussed.
- The role of temperature on the branching ratios of decarboxylation vs dehydration is elucidated.
Files
AA-ketene.txt
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