Structural study of iron cluster - hetero diene chain S - C - N – C X-ray ORTEP and 13C nuclear magnetic resonance diagramn cluster - hetero diene chain S - C - N – C X-ray ORTEP and 13C nuclear magnetic resonance diagram
Authors/Creators
- 1. Research Unit Materials, Processes and Environment / M'Hamed Bougara University, Boumerdes, Algeria, Avenue de l'indépendance, 35000, Boumerdes
- 2. Research Unit in Analysis and Technological Development in the Environment, Research Center in Physicochemical Analysis, Bousmail, Algeria, BP 384, Zone Industrielle Bou-Ismail RP 42004 Tipaza, Algeria
Description
Sulphur-iron clusters, like nitrogen-iron clusters, are at the heart of important biochemical movements in cellular life, such as ferredoxin and porphyrin. Knowing the structural nature of this type of clusters is fundamental for the understanding of pathological anomalies of physiological order, understanding the phenomena of chemical signalling, transport and cellular depollution in part. The structural study of the S-C-N-C - iron carbonyl model allows us to understand the nature of the physicochemical interactions of the different atoms of the S-C-N-C chain with the iron atom. After the synthesis of the butadiene-iron carbonyl complex, X-ray PET is studied. IR, SDM and 1H and 13C NMR analysis is presented. After examination of the spectra, some types of chemical bonds are confirmed