Published December 31, 1938 | Version v1

ON THIOALDEHYDES AND THIOKETONES. PART II.

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A general method for the synthesis of thiophens and endothiothiophens has been described. The antocondensation of certain a.keto-alcohols followed by an internal rearrrangement in an atmosphere of H2S furnishes endothiothiophens. A new synthesis of thiophens has also been achieved by an application of this reaction to unsaturated \(\gamma\)-diketones.

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