Published October 18, 2021 | Version v2

Comparative Evaluation of Light-Driven Catalysis

  • 1. Ulm University
  • 2. Friedrich Schiller-University Jena

Description

Light-driven homogeneous and heterogeneous catalysis requires a complex interplay between light-absorption, charge-separation, charge transfer and catalytic turnover. Optical and irradiation parameters as well as reaction engineering aspects play major roles in controlling catalytic performance. This multitude of factors makes it difficult to objectively compare light-driven catalysts and provide an unbiased performance assessment. This Scientific Perspective highlights the importance of collecting and reporting experimental data in homogeneous and heterogeneous light-driven catalysis. A critical analysis of the benefits and limitations of the commonly used experimental indicators is provided. Data collection and reporting according to FAIR principles is discussed in the context of future automated data analysis. The authors propose a minimum dataset as a basis for unified collecting and reporting of experimental data in homogeneous and heterogeneous light-driven catalysis. The community is encouraged to support the future development of this parameter list through an open online repository.

Notes

Financial support by the Deutsche Forschungsgemeinschaft DFG via the Transregio-Collaborative Research Center TRR 234 "CataLight" (project no: 364549901, projects: A1, A4, A5, B3, B8, C6), the Priority Program SPP 2102 "Light-controlled reactivity in metal complexes" (project nos: 359737763, 404382951, 404530119), as well as the Vector Stiftung (project number P2019-0110) is gratefully acknowledged.

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