Kirkwood-Buff Parameters for Binary Mixture

Department of Chemistry, University of Kalyani, Kalyani-741 235

Manuscript received 6 July 1993, revised 10 December 1993, accepted 17 February 1994

Kirkwood-Buff parameters have been calculated for four binary mixtures : (1) C₆H₆ + C₆H₁₂, (2) C₆H, + CCI₄, (3) C₆H₆ + C₂H₄CI₄, (4) CHCI₃ + (CH₃)₂CO with the help of thermodynamic quantities like partial molar volume, isothermal compressibility etc. Finally, the molecular interactions within the mixtures have been discussed with the help of these parameters.