Preparation of MnO2@silver-X zeolite nanocomposite adsorbent for the detoxification of toxic blister agent simulant 2-chloroethyl phenyl sulfide (2-CEPS)
Authors/Creators
- 1. Depatment of Inorganic Chemistry, Faculty of Chemistry & Petroleum Sciences, Shahid Beheshti University(SBU), Iran
- 2. Department of Chemistry, Lorestan University, Khorramabad, Iran
- 3. Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran
- 4. Department of Chemistry, Golestan University, Gorgan, Iran
Description
In this present research, MnO2 nanoparticles@silver-X zeolite nanocomposite adsorbent was manufactured by the impregnation method and identified using Scanning electron microscopy (SEM), Atomic adsorption spectrometry (AAS), X-ray fluorescence (XRF) spectroscopy, X-ray diffraction (XRD) spectroscopy and Fourier transform infrared spectroscopy (FT-IR) techniques. In the next step, the MnO2@AgX nanocomposite performance for the detoxification of blister agent simulant 2-chloroethyl phenyl sulfide (2-CEPS) was evaluated by applying GC-FID. The GC-FID achieved data displayed that this agent simulant was completely detoxified over the MnO2@AgX nanocomposite surface in n-hexane solvent after 12h. The both hydrolysis and elimination products namely 2-hydroxyl ethyl phenyl sulfide (2-HEPS) and phenyl vinyl sulfide (PVS) from 2-CEPS molecule were also identified by GC-MS analysis, respectively.
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Preparation of MnO2@silver-X zeolite nanocomposite adsorbent for the detoxification of toxic blister agent simulant 2-chloroethyl phenyl sulfide (2-CEPS).pdf
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