Published November 25, 2021 | Version v1

ACTIVATED CARBON DERIVED FROM BALAM KHIRA (KIGELIA AFRICANA) USED FOR REMOVAL OF Pb (II) ION FROM ITS AQUEOUS SOLUTION

  • 1. Department of Chemistry, Dayanand Anglo-Vedic (PG) College, Chhatrapati Shahu Ji Maharaj University, Kanpur, U. P. 208001
  • 2. Department of Chemistry, Dayanand Brajendra Swarup PG College, Chhatrapati Shahu Ji Maharaj University, Kanpur, U.P. 208006

Description

A low cost activated carbon derived from the fruit of Kigelia Africana (KA), was characterized for effective removal of Pb (II) from its aqueous solution. The derived carbon from Kigelia Africana (CKA) had micro porous and meso porous pore size distribution with high surface area (799 m2 g-1) and high carbon content (79.42 %).The batch experiments are carried out to investigate the effect of process parameters such as solution concentration, pH, temperature, contact time, CKA amount on adsorption. The maximum adsorption was found at pH 5.0 (on 97 % for 2.5 g/l CKA in 50 mg/l Pb (II) initial concentration). The Langmuir, Freundlich and Temkin models were modeled to evaluate the equilibrium adsorption data. The adsorption isotherm data was best fitted by Langmuir model with adsorption capacity 79.87 mg/g (R2 = 0.99) at 300 C. Thermodynamic study demonstrates spontaneous and endothermic nature of the adsorption. Kinetic studies were examined using different kinetic models (Lagergren first order and pseudo second order) and found pseudo second order kinetic data are well fitted for adsorption process.

 

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