Published February 13, 2018 | Version v1
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Data from: Incorporation of Mn2+ into CdSe quantum dots by chemical bath co-deposition method for photovoltaic enhancement of quantum dot-sensitized solar cells

  • 1. Yangtze University
  • 2. Hubei University

Description

A photoelectric conversion efficiency (PCE) of 4.9% was obtained under 100 mWcm−2 illumination by using quantum-dot-sensitized solar cells (QDSSCs) using a CdS/Mn:CdSe sensitizer. CdS quantum dots (QDs) were deposited on the TiO2 mesoporous oxide film by successive ionic layer absorption and reaction. Mn2+ doping into CdSe QDs is an innovative and simple method—chemical bath co-deposition, that is, mixing the Mn ion source with CdSe precursor solution for Mn:CdSe QD deposition. Compared with the CdS/CdSe sensitizer without Mn2+ incorporation, the PCE was increased from 3.4% to 4.9%. The effects of Mn2+ doping on the chemical, physical, and photovoltaic properties of the QDSSCs were investigated by energy dispersive spectrometry, absorption spectroscopy, photocurrent density–voltage characteristics, and electrochemical impedance spectroscopy. Mn-doped CdSe QDs in QDSSCs can obtain superior light absorption, faster electron transport, and slower charge recombination than CdSe QDs.

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Is cited by
10.1098/rsos.171712 (DOI)