Published August 12, 2020 | Version v1

Spectral characterization of LiYbF4 upconverting nanoparticles

  • 1. Institute National de la Recherche Scientifique, Centre Énergie Matériaux Télécommunication, Université du Québec, 1650 Boul. Lionel-Boulet, Varennes, Québec J3X 1S2, Canada
  • 2. Institute of Sensors, Signals and Systems, Heriot-Watt University, Edinburgh, EH14 4AS, UK
  • 3. Fluorescence Imaging Group (FIG), Departamento de Física de Materiales, Facultad de Ciencias, Universidad Autónoma de Madrid, C/ Francisco Tomás y Valiente 7, Madrid 28049, Spain.

Description

In this work, rare-earth-based nanoparticles based on LiYbF4 and doped with Er3+, Tm3+ and Ho3+ were investigated. The effect of the concentration of the dopant ions was thoroughly studied from a spectroscopic standpoint under 980 nm excitation. The upconversion emission that originates from the absorption of the optical energy from the Yb3+ ions in the crystal lattice and the subsequent energy transfer to the other rare earth in the lattice (i.e., Er3+, Tm3+ or Ho3+) highly depends on the concentration of the latter ion. Overall, the findings in this manuscripts provide important insights into the properties and rational design of upconverting nanoparticles.

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Funding

European Commission
LANTERNS - LANTHANIDE ION DOPING OF TERNARY QUANTUM DOTS 797945