Published January 13, 2021 | Version v1

Pd-based bimetallic catalysts in hydrogenation with parahydrogen

  • 1. International Tomography Center SB RAS
  • 2. N.D. Zelinsky Institute of Organic Chemistry RAS

Description

Here is raw NMR data obtained while different Pd-based bimetallic catalysts were tested in gas-phase propyne hydrogenation with parahydrogen. 

Folder PdAg Pd Ag:

1) spectra 1-13 - bimetallic Pd-Ag catalyst was tested at different gas flow rates at 100 C;

2) spectra 14-21 - bimetallic Pd-Ag catalyst was tested at different gas flow rates at 200 C;

3) spectra 22-29 - bimetallic Pd-Ag catalyst was tested at different gas flow rates at 300 C;

4) spectra 30-32 - monometallic Ag catalyst was tested at different flow rates at 200 C;

5) spectra 33-38 - monometallic Ag catalyst was tested at different flow rates at 300 C;

6) spectra 39-47 - monometallic Pd catalyst was tested at different flow rates at 300 C;

7) spectra 48-55 - monometallic Pd catalyst was tested at different flow rates at 200 C;

8) spectra 56-63 - monometallic Pd catalyst was tested at different flow rates at 100 C;

9) spectra 64-67 - monometallic Pd catalyst was tested at different flow rates at 50 C.

Folder PdIn:

1) spectra 300-308 - bimetallic PdIn catalyst was tested at different flow rates at 100 C;

2) spectra 309-318 - bimetallic PdIn catalyst was tested at different flow rates at 200 C;

3) spectra 319-326 - bimetallic PdIn catalyst was tested at different flow rates at 300 C;

4) spectra 327-334 - bimetallic PdIn catalyst was tested at different flow rates at 400 C;

5) spectra 335-342 - bimetallic PdIn catalyst was tested at different flow rates at 500 C;

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