Published March 15, 2016 | Version v2
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Synthesis of dehydroacetic acid derivatives with chromophoric chains and their complexes with zirconium phthalocyanine

Description

Dyes based on derivatives of dehydroacetic acid were synthesized by its condensation with aldehydes. The
synthesized compounds were used to prepare out-of-plane complexes with zirconium phthalocyanine. The
composition, structure and spectral properties of the compounds were characterized by NMR and UV-Vis
spectroscopy. An additional chromophore in the macrocyclic system is manifested by the broadening of the
Soret band, its bathochromic shift and appearance of shoulder on the red side of the Soret band.

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Additional details

Funding

European Commission
METCOPH - Metallocomplexes of macrocyclic compounds for photonic devices 645628