Published June 14, 2013 | Version v1
Journal article Open

From Simple Furans to Complex Nitrogen-Bearing Aromatic Polycycles by Means of a Flexible and General Reaction Sequence Initiated by Singlet Oxygen

Description

A new and general one-pot reaction sequence initiated by singlet oxygen that transforms simple furan substrates into complex nitrogen-bearing aromatic polycycles having all the structural features of a number of important natural products is reported. The reaction sequence itself uses mild conditions and has wide functional group tolerance.

Notes

This is the pre-peer reviewed version of the following article: Chemistry a European Journal 2013, 19, 10119 – 10123, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201301571/abstract

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Funding

European Commission
SINOXYGEN - Advancing the Green Chemistry of Singlet Oxygen and Applying it to Synthetic Challenges 277588