Published August 31, 2021
| Version v1
Dataset
Open
Table 1 1 H NMR spectroscopic data for compounds 1, 2, 3, 4 in Kangaroo Island propolis types originating from two Lepidosperma species and Dodonaea humilis
Authors/Creators
- 1. * & Sydney Pharmacy School, Faculty of Medicine and Health, The University of Sydney, New South Wales, Australia
Description
Table 1 1 H NMR spectroscopic data for compounds 1, 2, 3, 4, and 5 (400 MHz, δ in ppm and J values (Hz) in parentheses).
| H | Comp. 1 a | Comp. 2 a | Comp. 3b | Comp. 4b | Comp. 5b |
|---|---|---|---|---|---|
| 1 | – | – | – | – | – |
| 2 | 5.37 dd (8.3, 4.8) | 7.32 m | 7.31 d (2.0) | 7.04 d (8.6) | 7.04 d (8.6) |
| 3 | 3.25 dd (14.3, 4.8), 3.19 dd (14.3, 8.3) | – | – | 6.69 d (8.6) | 6.69 d (8.6) |
| 4 | – | – | – | – | – |
| 5 | – | 6.82 d (8.8) | 6.77 d (8.2) | 6.69 d (8.6) | 6.69 d (8.6) |
| 6 | – | 7.32 m | 7.27 dd (8.2,2.0) | 7.04 d (8.6) | 7.04 d (8.6) |
| 1′ | – | – | – | – | – |
| 2′ | 7.25–7.33 m | 6.29 d (15.9) | 6.24 d (16.0) | – | – |
| 3′ | 7.25–7.33 m | 7.71 d (15.9) | 7.57 d (16.0) | 6.25 s | 6.43 s |
| 4′ | 7.25–7.33 m | – | – | – | – |
| 5′ | 7.25–7.33 m | – | – | – | – |
| 6′ | 7.25–7.33 m | – | – | 7.47 s | 7.51 s |
| 1′′ | – | 3.37 bd (7.2) | 3.32 bd (6.9) | 3.25 bd (7.2) | 3.26 bd (7.3) |
| 2′′ | 6.46 d (16.0) | 5.31 bt (7.7) | 5.40 bt (6.9) | 5.56 bt (7.4) | 5.51 bt (7.4) |
| 3′′ | 7.69 d (16.0) | – | – | – | – |
| 4′′ | – | 2.06 m | 2.10 m, 2.32 m | 3.96 s | 3.95 s |
| 5′′ | – | 1.42 m | 1.41 m, 1.79 m | 1.74 s | 1.73 s |
| 6′′ | – | 1.41 m, 1.64 m | 3.27 dd (10.6, 1.6) | – | – |
| 7′′ | – | 2.46 m | – | – | – |
| 8′′ | – | – | 1.16 s | – | – |
| 9′′ | – | 1.15 d (7.1) | 1.13 s | – | – |
| 10′′ | – | 1.75 bs | 1.74 bs | – | – |
| 1′′′ | – | – | – | – | – |
| 2′′′ | 7.51 m | – | – | – | – |
| 3′′′ | 7.39 m | – | – | – | – |
| 4′′′ | 7.39 m | – | – | – | – |
| 5′′′ | 7.39 m | – | – | – | – |
| 6′′′ | 7.51 m | – | – | – | – |
| α | – | – | – | 3.13 t (7.6) | 3.17 t (7.5) |
| β | – | – | – | 2.89 t (7.7) | 2.90 t (7.6) |
| C=O | – | – | – | – | – |
| 1-OMe | 3.74 s | – | – | – | – |
| 4′-OMe | – | – | – | – | 3.86 s |
| 8′′-OMe | – | 3.68 s | – | – | – |
a Measured in CDCl relative to TMS.
3 b Measured in CD OD relative to TMS.
Notes
Published as part of King, Douglas I., Hamid, Kaiser, Tran, Van H., Duke, Rujee K. & Duke, Colin C., 2021, Kangaroo Island propolis types originating from two Lepidosperma species and Dodonaea humilis, pp. 3 in Phytochemistry (112800) 188 on page 3, DOI: 10.1016/j.phytochem.2021.112800, http://zenodo.org/record/8259223
Files
Files
(5.0 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:e61db139b0776cb5c612c375215e6078
|
5.0 kB | Download |
System files
(10.9 kB)
| Name | Size | Download all |
|---|---|---|
|
md5:9899313097c024a6d67844380129fe86
|
10.9 kB | Download |